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Author:

Li, Ming (Li, Ming.) | Xi, Xiaoli (Xi, Xiaoli.) (Scholars:席晓丽) | Nie, Zuoren (Nie, Zuoren.) (Scholars:聂祚仁) | Ma, Liwen (Ma, Liwen.) | Liu, Qingqing (Liu, Qingqing.)

Indexed by:

Scopus SCIE

Abstract:

In this work, the electrochemical behavior of cobalt ion was investigated using an inert graphite rod electrode at 1073 K in NaF-KF-CoF2 (1 wt%) molten salt system. Several transient electrochemical techniques, such as cyclic voltammetry, square wave voltammetry, and chronopotentiometry, were used. Results showed that electroreduction of Co2+ to Co is a reversible, one-step, two-electron transfer. The diffusion coefficient of Co2+ was investigated with cyclic voltammetry, square wave voltammetry, and chronopotentiometry, and results from the considered methods exhibited fair agreement. Electrodeposition of cobalt was performed at -0.3 V versus Pt at 1073 K for 4 h in a NaFKF-CoF2 (1 wt%) melt. The deposits were examined using X-ray diffraction and X-ray fluorescence, and results confirmed the obtained deposits as metallic cobalt. The present study aims to provide a theoretical reference for electrolysis of WC-Co hard metal scraps in molten salt.

Keyword:

Electrochemistry Molten salts Diffusion coefficient Cobalt

Author Community:

  • [ 1 ] [Li, Ming]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Xi, Xiaoli]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Nie, Zuoren]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Ma, Liwen]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Liu, Qingqing]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 席晓丽

    [Xi, Xiaoli]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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Source :

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE

ISSN: 1452-3981

Year: 2018

Issue: 5

Volume: 13

Page: 4208-4222

1 . 5 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:192

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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