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Abstract:
TiO2 with Nanoring/Nanotube (R/T) hierarchical structure can be prepared by tuning the oxidation time and oxidation voltage in the second step anodization. The resulting multiabsorption oscillating peaks in the visible light region present a strong dependence on the tube length which are derived from the interference of light reflected from the top nanorings and the bottom Ti substrate, and the optical path length in TiO2 R/T hierarchical structure can be estimated as about 2 mu m. The tube length of the as-prepared TiO2 photoelectrode affects greatly its saturation photocurrent density, and the different tube-wall thickness can change the photocurrent-saturation potential. Under simulated AM 1.5 irradiation (100 mW/cm(2)), TiO2 R/T hierarchical structure with tube diameters of 20-40 nm and tube length of about 1.5 mu m shows higher photocurrent density and hydrogen production rate at the bias of 0 V (vs. Ag/AgCl). The results from the IPCE plots and I-t curves verify that TiO2 R/T hierarchical structure can exhibit the visible light activity, which is more related to the absorption induced by the defects rather than oscillating peaks. Based on the unique multiple light reflection in TiO2 R/T hierarchical structure, surface treatment will pave a way for the better utilization of oscillating peaks in the visible light region. (C) 2017 Elsevier B.V. All rights reserved.
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APPLIED SURFACE SCIENCE
ISSN: 0169-4332
Year: 2018
Volume: 430
Page: 496-504
6 . 7 0 0
JCR@2022
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:260
JCR Journal Grade:1
Cited Count:
WoS CC Cited Count: 9
SCOPUS Cited Count: 9
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 7
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