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Author:

Zhang, Sheng (Zhang, Sheng.) | Lian, Fei (Lian, Fei.) | Xue, Mengyu (Xue, Mengyu.) | Qin, Tengteng (Qin, Tengteng.) | Li, Lijun (Li, Lijun.) | Zhang, Xu (Zhang, Xu.) | Xu, Kun (Xu, Kun.)

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Abstract:

A scalable and efficient electrocatalytic dehydrogenative esterification is reported. With an indirect electrolysis strategy, both intra- and intermolecular-type reactions were amenable to this practical method. With nBu(4)NI as the catalyst, undesired decarboxylation and Baeyer Villiger oxidation were suppressed. More importantly, this novel method provided reliable and direct access to the natural product cytosporanone A on a gram scale.

Keyword:

Author Community:

  • [ 1 ] [Zhang, Sheng]Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China
  • [ 2 ] [Lian, Fei]Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China
  • [ 3 ] [Xue, Mengyu]Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China
  • [ 4 ] [Qin, Tengteng]Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China
  • [ 5 ] [Li, Lijun]Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China
  • [ 6 ] [Zhang, Xu]Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China
  • [ 7 ] [Xu, Kun]Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China
  • [ 8 ] [Lian, Fei]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Zhang, Sheng]Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China;;[Xu, Kun]Nanyang Normal Univ, Coll Chem & Pharmaceut Engn, Nanyang 473061, Peoples R China

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Source :

ORGANIC LETTERS

ISSN: 1523-7060

Year: 2017

Issue: 24

Volume: 19

Page: 6622-6625

5 . 2 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:212

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 55

SCOPUS Cited Count: 55

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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