Using　state-of-the-art　atomic　scale　super　energy　dispersive　X-ray　spectroscopy　and　high　angle　annular　dark　field　imaging　this　study　reveals　the　elemental　partitioning　preference　between　the　gamma＇　and　gamma　phases　in　a　Co-Al-W-Ti-Ta　superalloy　and　the　site　preference　of　its　alloying　elements　in　the　ordered　L1(2)　gamma＇　phase.　A　semi-quantitative　analysis　of　atomic　column　compositions　in　the　ordered　L1(2)　gamma＇　structure　is　provided.　Co　atoms　were　found　to　occupy　the　{1/2,　1/2,　0}　face-center　positions　whereas　Al,　W,　Ti　and　Ta　atoms　prefer　to　occupy　the　{0,　0,　0}　cube　corner　positions　in　the　L1(2)　gamma　phase.　These　findings　agree　well　with　predictions　from　first　principles　simulations　in　the　literature.