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Author:

Guo, Hongxia (Guo, Hongxia.) (Scholars:郭红霞) | Wang, Junhua (Wang, Junhua.) | Fang, Qianrong (Fang, Qianrong.) | Zhao, Yun (Zhao, Yun.) | Gu, Shuang (Gu, Shuang.) | Zheng, Jie (Zheng, Jie.) | Yan, Yushan (Yan, Yushan.)

Indexed by:

Scopus SCIE

Abstract:

Here we report a new anion conducting covalent organic framework (COF). Quaternary ammonium (QA) ions are covalently tethered onto the pore walls of COF 1,3,5-triformylphloroglucinol-o-tolidine (TpBD-Me) through bromination and quaternization. The QA-functionalized COF shows a bicarbonate conductivity of 5.3 mS cm(-1) at 20 degrees C and 27.0 mS cm(-1) at 80 degrees C, accompanied by 3.3 wt% water uptake and <1.0% swelling ratio at 20 degrees C. This QA-functionalized COF provides a new option for anion conducting materials.

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Author Community:

  • [ 1 ] [Guo, Hongxia]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Guo, Hongxia]Univ Delaware, Dept Chem & Biomol Engn, Ctr Catalyt Sci & Technol, Newark, DE 19716 USA
  • [ 3 ] [Wang, Junhua]Univ Delaware, Dept Chem & Biomol Engn, Ctr Catalyt Sci & Technol, Newark, DE 19716 USA
  • [ 4 ] [Fang, Qianrong]Univ Delaware, Dept Chem & Biomol Engn, Ctr Catalyt Sci & Technol, Newark, DE 19716 USA
  • [ 5 ] [Zhao, Yun]Univ Delaware, Dept Chem & Biomol Engn, Ctr Catalyt Sci & Technol, Newark, DE 19716 USA
  • [ 6 ] [Gu, Shuang]Univ Delaware, Dept Chem & Biomol Engn, Ctr Catalyt Sci & Technol, Newark, DE 19716 USA
  • [ 7 ] [Zheng, Jie]Univ Delaware, Dept Chem & Biomol Engn, Ctr Catalyt Sci & Technol, Newark, DE 19716 USA
  • [ 8 ] [Yan, Yushan]Univ Delaware, Dept Chem & Biomol Engn, Ctr Catalyt Sci & Technol, Newark, DE 19716 USA
  • [ 9 ] [Fang, Qianrong]Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China

Reprint Author's Address:

  • [Yan, Yushan]Univ Delaware, Dept Chem & Biomol Engn, Ctr Catalyt Sci & Technol, Newark, DE 19716 USA

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Source :

CRYSTENGCOMM

ISSN: 1466-8033

Year: 2017

Issue: 33

Volume: 19

Page: 4905-4910

3 . 1 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:212

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 56

SCOPUS Cited Count: 57

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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