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Abstract:
This paper reports the electrodeposition of Pd in the room-temperature ionic liquid 1-ethyl-3methylimidazolium trifluoroacetate ([emim] TA). The electrochemical behavior of PdC(l)2 in [emim] TA was investigated using cyclic voltammetry. Cyclic voltammograms were recorded at various scan rates and temperatures and showed that the reduction of Pd was irreversible. The diffusion coefficient of PdCl2 in [emim] TA increased with increasing temperature and the diffusion activation energy was determined to be 43.66 KJ mol-1. The optimum parameters of Pd electrodeposition in [emim] TA were determined through single-factor experiments. The surface morphology of the deposits was analyzed via scanning electron microscopy and the crystal structure of metallic Pd was confirmed through X-ray diffraction.
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INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
ISSN: 1452-3981
Year: 2017
Issue: 2
Volume: 12
Page: 1130-1145
1 . 5 0 0
JCR@2022
ESI Discipline: CHEMISTRY;
ESI HC Threshold:212
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 3
SCOPUS Cited Count: 3
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 7
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