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Author:

Xi, Xiaoli (Xi, Xiaoli.) (Scholars:席晓丽) | Song, Shanshan (Song, Shanshan.) | Nie, Zuoren (Nie, Zuoren.) (Scholars:聂祚仁) | Ma, Liwen (Ma, Liwen.)

Indexed by:

Scopus SCIE

Abstract:

This paper reports the electrodeposition of Pd in the room-temperature ionic liquid 1-ethyl-3methylimidazolium trifluoroacetate ([emim] TA). The electrochemical behavior of PdC(l)2 in [emim] TA was investigated using cyclic voltammetry. Cyclic voltammograms were recorded at various scan rates and temperatures and showed that the reduction of Pd was irreversible. The diffusion coefficient of PdCl2 in [emim] TA increased with increasing temperature and the diffusion activation energy was determined to be 43.66 KJ mol-1. The optimum parameters of Pd electrodeposition in [emim] TA were determined through single-factor experiments. The surface morphology of the deposits was analyzed via scanning electron microscopy and the crystal structure of metallic Pd was confirmed through X-ray diffraction.

Keyword:

Palladium Electrodeposition Electrochemical behavior [emim] TA

Author Community:

  • [ 1 ] [Xi, Xiaoli]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Song, Shanshan]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Nie, Zuoren]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Ma, Liwen]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 席晓丽

    [Xi, Xiaoli]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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Source :

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE

ISSN: 1452-3981

Year: 2017

Issue: 2

Volume: 12

Page: 1130-1145

1 . 5 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:212

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 7

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