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学者姓名：叶青
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Abstract ：
Photocatalytic CO2 reduction technology plays a significant role in the energy and environmental sectors, highlighting the necessity for developing high-efficiency and stable catalysts. In this study, a novel photocatalyst, x NiCo 2 O 4 /CN (x = 1, 3, and 5 wt%), was synthesized by depositing zeolitic imidazolate framework-67 (ZIF-67)derived nickel cobaltate (NiCo2O4) hollow nanocages onto porous graphitic carbon nitride (g-C3N4, CN) nano sheets for photocatalytic CO2 reduction. Under visible light irradiation, the resulting 3NiCo2O4/CN photocatalyst demonstrated exceptional CO yields of up to 2879.5 mu mol g- 1 h- 1 , surpassing those of NiCo2O4 and CN alone by factors of 3.3 and 11.6, respectively. The introduction of hollow NiCo2O4 nanocages increased the specific surface area of the material and enhanced the number of active sites, while strengthening visible light absorption. The creation of a built-in electric field, induced by the Fermi level difference between the two materials, was confirmed through ultraviolet photoelectron spectroscopy (UPS) characterization. This resulted in the formation of a Z-scheme heterojunction, significantly enhancing the separation and migration of photogenerated charge carriers. Notably, 3NiCo2O4/CN exhibits excellent stability during long-term photocatalytic reactions, ensuring reliable performance for practical applications. This study offers novel insights and methodologies for developing efficient photocatalytic CO2 reduction catalysts.
Keyword ：
Z-scheme heterojunction Z-scheme heterojunction Graphitic carbon nitride Graphitic carbon nitride Nickel cobaltate Nickel cobaltate Photocatalytic CO2 reduction Photocatalytic CO2 reduction
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| GB/T 7714 | Meng, Fanwei , Qu, Chao , Wang, Lanyang et al. ZIF-67-derived NiCo2O4 hollow nanocages coupled with g-C3N4 nanosheets as Z-scheme photocatalysts for enhancing CO2 reduction [J]. | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2025 , 684 : 492-502 . |
| MLA | Meng, Fanwei et al. "ZIF-67-derived NiCo2O4 hollow nanocages coupled with g-C3N4 nanosheets as Z-scheme photocatalysts for enhancing CO2 reduction" . | JOURNAL OF COLLOID AND INTERFACE SCIENCE 684 (2025) : 492-502 . |
| APA | Meng, Fanwei , Qu, Chao , Wang, Lanyang , Yang, Decai , Zhao, Zezhong , Ye, Qing . ZIF-67-derived NiCo2O4 hollow nanocages coupled with g-C3N4 nanosheets as Z-scheme photocatalysts for enhancing CO2 reduction . | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2025 , 684 , 492-502 . |
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Abstract ：
The dissociation of water is essential to water gas shift (WGS) reaction, and the presence of oxygen vacancies can facilitate this key step. Herein, a series of perovskite supported Pd single atoms catalysts were prepared via deposition precipitation method. The incorporation of Pd single atoms can effectively promote the formation of oxygen vacancy on the surface of the catalyst, improving the low temperature reducibility, the ratio of Mn4+ / Mn3+ and O-ads/O-lat compared with support. Among all samples, 0.82 Pd/La0.5Ca0.5MnO3/SBA-15 with the most oxygen vacancies presented 83.6 % CO conversion at 400 degrees C, specific reaction rate (0.54 mol(CO) g(Pd)(-1) h(-1) ), and TOF (3.77.10(-2) s(-1)). DFT calculation proved that Pd doping can effectively decreased energy barrier of H2O dissociation, and promoted the formation of oxygen vacancies. This work provides experimental and theoretical insights into the rational design of highly active perovskite supported Pd single atom catalysts for WGS reaction.
Keyword ：
DFT calculation DFT calculation Water gas shift reaction Water gas shift reaction Perovskite Perovskite Pd single atom Pd single atom Oxygen vacancy Oxygen vacancy
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| GB/T 7714 | Xiao, Yang , Qu, Chao , Zhang, Jingjing et al. Promoted oxygen vacancy formation by highly dispersed Pd single atoms anchored on SBA-15 decorated La0.5Ca0.5MnO3 for efficient water gas shift reaction [J]. | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2025 , 13 (2) . |
| MLA | Xiao, Yang et al. "Promoted oxygen vacancy formation by highly dispersed Pd single atoms anchored on SBA-15 decorated La0.5Ca0.5MnO3 for efficient water gas shift reaction" . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 13 . 2 (2025) . |
| APA | Xiao, Yang , Qu, Chao , Zhang, Jingjing , Chen, Xi , Wang, Wenjin , Zheng, Xuelong et al. Promoted oxygen vacancy formation by highly dispersed Pd single atoms anchored on SBA-15 decorated La0.5Ca0.5MnO3 for efficient water gas shift reaction . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2025 , 13 (2) . |
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Abstract ：
As a novel medium-temperature CO(2 )adsorbent, K+ doped and graphitic carbon nitride modified layered double oxide composite (xK/CN-LDO, x = 15, 20, and 25 wt%) were prepared via in-situ synthesis and impregnation methods. Their adsorption performance was evaluated by thermal gravimetric analyzer. g-C3N4-modified LDO (CN-LDO) exhibited a CO2 adsorption capacity of 0.46 mmol/g, 1.39 times higher than the 0.33 mmol/g observed for LDO. This enhancement was attributed to the increased specific surface area and the exposure of additional extractable sites. Further doping with K significantly enhanced the adsorption uptake of xK/CN-LDO. Notably, 20 K/CN-LDO achieved the highest CO2 adsorption uptake of 0.82 mmol/g, representing a 2.48-fold increase compared to LDO. This further enhancement can be ascribed to K's ability to alter the distribution of chemical adsorption sites, thereby providing an optimal number of basic sites. In-situ DRIFTS analysis revealed that CO(2 )predominantly existed in the form of carbonate species, while adsorption kinetics studies show that the dominant mechanism is chemical adsorption, with external diffusion being the primary adsorption process. Furthermore, 20 K/CN-LDO exhibited significantly higher regeneration efficiency of 72.4 % after 10 cycles, showcasing its promising practical prospects for application in the SEWGS process.
Keyword ：
Adsorption mechanism Adsorption mechanism Graphitic carbon nitride Graphitic carbon nitride CO 2 adsorption capacity CO 2 adsorption capacity Layered double oxide Layered double oxide
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| GB/T 7714 | Wang, Lanyang , Qu, Chao , Meng, Fanwei et al. K+ doped graphitic carbon nitride modified layered double oxide nanocomposite towards high-efficiency CO2 adsorption at intermediate temperature [J]. | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2024 , 12 (5) . |
| MLA | Wang, Lanyang et al. "K+ doped graphitic carbon nitride modified layered double oxide nanocomposite towards high-efficiency CO2 adsorption at intermediate temperature" . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 12 . 5 (2024) . |
| APA | Wang, Lanyang , Qu, Chao , Meng, Fanwei , Yang, Fan , Ye, Qing . K+ doped graphitic carbon nitride modified layered double oxide nanocomposite towards high-efficiency CO2 adsorption at intermediate temperature . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2024 , 12 (5) . |
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Abstract ：
Lead (Pb) is a heavy metal commonly found in industrial exhaust gases, which can reduce catalytic activity of a catalyst for the NH3-SCR reaction. In this study, 4.0 wt% Mn-loaded Fe-pillared interlayer clay (4Mn/Fe-PILC) and its Co-modified catalyst (2Co-4Mn/Fe-PILC) were prepared, in the meanwhile the 4Mn/Fe-PILC-Pb and 2Co-4Mn/Fe-PILC-Pb samples were also obtained using the impregnation method with a Pb(CH3COO)(2) aqueous solution. It was found that the addition of 2.0 wt% cobalt could significantly enhance Pb resistance of the 4Mn/Fe-PILC catalyst. The characterization results revealed that the doping of Co to Mn/Fe-PILC increased the surface Mn4+ species concentration, reducibility, and acid site amount, thereby improving Pb resistance of the catalyst. Furthermore, the in situ DRIFTS results demonstrated that Co modification enhanced the adsorption capacity of NH3 or NO, especially influenced formation of the NH3 intermediates and bridging nitrate species, which were also conducive to the improvement in Pb resistance of the catalyst.
Keyword ：
NH3-SCR NH3-SCR Co modification Co modification Pb resistance Pb resistance Nitrogen oxide Nitrogen oxide Pillared clay Pillared clay
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| GB/T 7714 | Wang, Xinpeng , Ye, Qing , Liu, Wenyi et al. Enhanced Resistance to Pb Poisoning of the Co-modified Mn/Fe-pillared Clay Catalysts for NH3-SCR at Low Temperatures [J]. | CHEMISTRYSELECT , 2023 , 8 (10) . |
| MLA | Wang, Xinpeng et al. "Enhanced Resistance to Pb Poisoning of the Co-modified Mn/Fe-pillared Clay Catalysts for NH3-SCR at Low Temperatures" . | CHEMISTRYSELECT 8 . 10 (2023) . |
| APA | Wang, Xinpeng , Ye, Qing , Liu, Wenyi , Meng, Fanwei , Yang, Fan , Zhang, Xin et al. Enhanced Resistance to Pb Poisoning of the Co-modified Mn/Fe-pillared Clay Catalysts for NH3-SCR at Low Temperatures . | CHEMISTRYSELECT , 2023 , 8 (10) . |
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Abstract ：
A series of RE-3Cu/Zr-PILC (RE = La, Ce, Nd, Eu) catalysts were prepared via an impregnation method and activities for NH3-SCR were evaluated. The physicochemical properties of each catalyst were explored using XRD, BET, H-2-TPR, NH3-TPD, XPS and in-situ DRIFTS techniques. The doping of RE had enhanced the NH3-SCR efficiency of 3Cu/Zr-PILC. Among them, the 6Ce-3Cu/Zr-PILC sample demonstrated exceptional performance, achieving NO conversion rates exceeding 90% within the temperature range of 250-350 degrees C. Moreover, it reached its peak NO conversion rate of 96.3% at 300 degrees C while maintaining an impressive resistance to SO2. According to the results of TPR, TPD and XPS analysis, the modification of RE (especially Ce) enhanced the redox properties, the surface acidity, the atomic ratio of Cu2+/Cu+ and the amount of surface chemisorbed oxygen in the 3Cu/Zr-PILC samples, all of these are favorable for the NH3-SCR reaction. Furthermore, in-situ DRIFTS analysis reveals that the NH3-SCR reaction of RE-3Cu/Zr-PILC samples at low temperatures is governed by the Langmuir-Hinshelwood (L-H) and Eley-Rideal (E-R) mechanisms, with the L-H mechanism being the predominant factor.
Keyword ：
Cu loading Cu loading low-temperature NH3-SCR low-temperature NH3-SCR Rare earth metal Rare earth metal Zr-PILC Zr-PILC
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| GB/T 7714 | Liu, Wenyi , Wang, Xinpeng , Qu, Chao et al. Rare Earth Metal (La, Ce, Nd, Eu) Doped Cu/Zr-PILC Catalysts for the Efficient NH3-SCR at Low Temperature [J]. | COMBUSTION SCIENCE AND TECHNOLOGY , 2023 . |
| MLA | Liu, Wenyi et al. "Rare Earth Metal (La, Ce, Nd, Eu) Doped Cu/Zr-PILC Catalysts for the Efficient NH3-SCR at Low Temperature" . | COMBUSTION SCIENCE AND TECHNOLOGY (2023) . |
| APA | Liu, Wenyi , Wang, Xinpeng , Qu, Chao , Meng, Fanwei , Yang, Fan , Zhang, Xin et al. Rare Earth Metal (La, Ce, Nd, Eu) Doped Cu/Zr-PILC Catalysts for the Efficient NH3-SCR at Low Temperature . | COMBUSTION SCIENCE AND TECHNOLOGY , 2023 . |
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Abstract ：
The xCN/Ce-OMS-2 (x is the nominal weight percentages of g-C3N4, x = 5.0, 10.0, and 15.0 wt%) catalysts were prepared via an in-situ synthesis method. Physicochemical properties of the as-prepared materials were measured by means of the XRD, TEM, SEM, BET, XPS, H2-TPR, NH3-TPD, and in-situ DRIFTS techniques, and their catalytic activities for the selective catalytic reduction of NOx with NH3 (NH3-SCR) at low temperatures were evaluated. Among all the catalysts, the 10CN/Ce-OMS-2 catalyst showed the widest temperature span for NH3-SCR reaction and the best resistance to SO2 poisoning. This may result from that the modification of g-C3N4 promoted the electron transfer in catalyst, not only increased the concentration of active Mn4+ species and chemisorbed oxygen species, but also improved the surface acidity of the catalyst. In-situ DRIFTS results further showed that the modification of g-C3N4 increased the amount of acid sites and enhanced the formation of NH3 or NO intermediates (i.e., monodentate and bidentate nitrate), which enhanced the reaction activity of the catalyst.
Keyword ：
G-C 3 N 4 modification G-C 3 N 4 modification OMS-2 OMS-2 NO x degradation NO x degradation Ceria doping Ceria doping
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| GB/T 7714 | Wang, Xinpeng , Qu, Chao , Liu, Wenyi et al. Enhanced low-temperature NH3-SCR performance by g-C3N4 modified Ce-OMS-2 catalyst [J]. | MICROPOROUS AND MESOPOROUS MATERIALS , 2023 , 361 . |
| MLA | Wang, Xinpeng et al. "Enhanced low-temperature NH3-SCR performance by g-C3N4 modified Ce-OMS-2 catalyst" . | MICROPOROUS AND MESOPOROUS MATERIALS 361 (2023) . |
| APA | Wang, Xinpeng , Qu, Chao , Liu, Wenyi , Meng, Fanwei , Yang, Fan , Zhang, Xin et al. Enhanced low-temperature NH3-SCR performance by g-C3N4 modified Ce-OMS-2 catalyst . | MICROPOROUS AND MESOPOROUS MATERIALS , 2023 , 361 . |
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Abstract ：
使用膜分离处理含油废水过程中,膜表面油污残留是制约应用的关键问题.对基膜表面进行亲水改性是提高分离效率与减少油污吸附的有效方法.本研究利用二苯甲酮光交联反应的特性,在基膜表面共价交联了含有2-甲基丙烯酰氧乙基磷酸胆碱(MPC)的两性离子聚合物,在大幅度提高了膜表面的亲水性的同时确保了亲水层的稳定性.油水分离膜呈现超亲水的性质,纯水通量可提高至4.7×104 L/(m2·h),通量恢复率从90.0％提升至99.8％.由于在基膜与两性离子聚合物间构建了稳定的共价键,膜表面的亲水性在强酸与强碱的清洗后依然能够保持,该研究为稳定的油水分离膜表面亲水改性提供了新策略.
Keyword ：
共价交联 共价交联 超亲水 超亲水 油水分离 油水分离 二苯甲酮 二苯甲酮 两性离子聚合物 两性离子聚合物
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| GB/T 7714 | 陈聪 , 杨紫云 , 赵博远 et al. 紫外诱导超亲水油水分离膜的构建及其性能研究 [J]. | 膜科学与技术 , 2022 , 42 (6) : 101-109 . |
| MLA | 陈聪 et al. "紫外诱导超亲水油水分离膜的构建及其性能研究" . | 膜科学与技术 42 . 6 (2022) : 101-109 . |
| APA | 陈聪 , 杨紫云 , 赵博远 , 刘巧鸿 , 叶青 , 安全福 . 紫外诱导超亲水油水分离膜的构建及其性能研究 . | 膜科学与技术 , 2022 , 42 (6) , 101-109 . |
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Abstract ：
To improve the removal capacity of NO + O2 effectively, the alkaline earth metal-doped order mesoporous carbon (A-C-FDU-15(0.001) (A = Mg, Ca, Sr and Ba)) and Mg-C-FDU-15(x) (x = 0.001−0.003) samples were prepared, and their physicochemical and NO + O2 adsorption properties were determined by means of various techniques. The results show that the sequence in (NO + O2) adsorption performance was as follows: Mg-C-FDU-15(0.001) (93.2 mg/g) > Ca-C-FDU-15(0.001) (82.2 mg/g) > Sr-C-FDU-15(0.001) (76.1 mg/g) > Ba-C-FDU-15(0.001) (72.9 mg/g) > C-FDU-15 (67.1 mg/g). Among all of the A-C-FDU-15(0.001) samples, Mg-C-FDU-15(0.001) possessed the highest (NO + O2) adsorption capacity (106.2 mg/g). The species of alkaline earth metals and basic sites were important factors determining the adsorption of NO + O2 on the A-C-FDU-15(x) samples, and (NO + O2) adsorption on the samples was mainly chemical adsorption. Combined with the results of (NO + O2)-temperature-programmed desorption ((NO + O2)-TPD) and in situ diffused reflectance infrared Fourier transform spectroscopy (DRIFTS) characterization, we deduced that there were two main pathways of (NO + O2) adsorption: one was first the conversion of NO and O2 to NO2 and then part of NO2 was converted to NO2− and NO3−; and the other was the direct oxidation of NO to NO2− and NO3−. © 2020
Keyword ：
Physicochemical properties Physicochemical properties Temperature programmed desorption Temperature programmed desorption Alkaline earth metals Alkaline earth metals Adsorption Adsorption Temperature Temperature Fourier transform infrared spectroscopy Fourier transform infrared spectroscopy Nitrogen oxides Nitrogen oxides Alkalinity Alkalinity
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| GB/T 7714 | Wu, Runping , Ye, Qing , Wu, Kai et al. Low-temperature (NO + O2) adsorption performance of alkaline earth metal-doped C-FDU-15 [J]. | Journal of Environmental Sciences (China) , 2021 , 103 : 172-184 . |
| MLA | Wu, Runping et al. "Low-temperature (NO + O2) adsorption performance of alkaline earth metal-doped C-FDU-15" . | Journal of Environmental Sciences (China) 103 (2021) : 172-184 . |
| APA | Wu, Runping , Ye, Qing , Wu, Kai , Dai, Hongxing . Low-temperature (NO + O2) adsorption performance of alkaline earth metal-doped C-FDU-15 . | Journal of Environmental Sciences (China) , 2021 , 103 , 172-184 . |
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Abstract ：
The Ni-loaded cryptomelane-type manganese oxide octahedral molecular sieve (OMS-2) catalysts (xNi/OMS-2: x = 1, 3, 5, and 10 wt%) were prepared by a pre-incorporation method. Physicochemical properties of the as-synthesized materials were characterized by means of various techniques, and their catalytic activities for CO, ethyl acetate, and toluene oxidation were evaluated.The loading of Ni played an important role in improving physicochemical propertiesof OMS-2. Among all of the samples, 5Ni/OMS-2 exhibited the best catalytic activity, with the T-90 being 155 degrees C for CO oxidation at a space velocity (SV) of 60,000 mL/(g center dot h), 225 degrees C for ethyl acetate oxidation at an SV of 240,000 mL/(g center dot h), and 300 degrees C for toluene oxidation at an SV of 240,000 mL/(g center dot h), which was due to its high Mn3+ content and O-ads concentration, good low-temperature reducibility and lattice oxygen mobility, and strong interaction between the Ni species and the OMS-2 support. In addition, catalytic mechanisms of the oxidation of three pollutants over 5Ni/OMS-2 were also studied. The oxidation of CO, ethyl acetate, and toluene over the catalysts took place first via the activated adsorption, then intermediates formation, and finally complete conversion of the formed intermediates to CO2 and H2O.
Keyword ：
CO oxidation CO oxidation cryptomelane-typemanganese oxide octahedral molecular sieve cryptomelane-typemanganese oxide octahedral molecular sieve supported nickel catalyst supported nickel catalyst ethyl acetate oxidation ethyl acetate oxidation toluene oxidation toluene oxidation
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| GB/T 7714 | Dong, Ning , Chen, Mengyue , Ye, Qing et al. Catalytic Elimination of Carbon Monoxide, Ethyl Acetate, and Toluene over the Ni/OMS-2 Catalysts [J]. | CATALYSTS , 2021 , 11 (5) . |
| MLA | Dong, Ning et al. "Catalytic Elimination of Carbon Monoxide, Ethyl Acetate, and Toluene over the Ni/OMS-2 Catalysts" . | CATALYSTS 11 . 5 (2021) . |
| APA | Dong, Ning , Chen, Mengyue , Ye, Qing , Zhang, Dan , Dai, Hongxing . Catalytic Elimination of Carbon Monoxide, Ethyl Acetate, and Toluene over the Ni/OMS-2 Catalysts . | CATALYSTS , 2021 , 11 (5) . |
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Abstract ：
The poisoning effects of alkali metals (K and Na) and alkaline earth metals (Ca and Mg) on catalytic performance of the 2Nb4Ce/Zr-PILC catalyst for the selective catalytic reduction of NOx with NH3 (NH3-SCR) were investigated, and physicochemical properties of the catalysts were characterized by means of the X-ray diffraction XRD (XRD), Brunner-Emmet-Teller (BET), hydrogen temperature-programmed reduction (H-2-TPR), X-ray Photoelectron Spectroscopy (XPS), ammonia temperature-programmed desorption (NH3-TPD), and in situ diffuse reflectance infrared Fourier transform spectroscopy (in situ DRIFTS) techniques. Doping of M (M = K, Na, Ca, and Mg) deactivated the 2Nb4Ce/Zr-PILC catalyst according to the sequence of 0.8 K > 0.8 Na > 0.8 Ca > 0.8 Mg (M/Ce molar ratio = 0.8). The characterization results showed that the decreases in redox ability, NH3 adsorption, Ce3+/Ce4+ atomic ratio, and amount of the chemisorbed oxygen (O-beta) were the important factors influencing catalytic activities of the alkali metal-and alkaline earth metal-doped samples. Consequently, compared with the Mg- and Ca-doped samples, doping of K caused the 2Nb4Ce/Zr-PILC sample to possess the lowest redox ability, NH3 adsorption, and amount of the O-beta species, which resulted in an obvious deactivation effect.
Keyword ：
selective catalytic reduction selective catalytic reduction poisoning poisoning surface acidity surface acidity alkali metal alkali metal alkaline earth metal alkaline earth metal NH3-SCR NH3-SCR
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| GB/T 7714 | Li, Chenxi , Cheng, Jin , Ye, Qing et al. Poisoning Effects of Alkali and Alkaline Earth Metal Doping on Selective Catalytic Reduction of NO with NH3 over the Nb-Ce/Zr-PILC Catalysts [J]. | CATALYSTS , 2021 , 11 (3) . |
| MLA | Li, Chenxi et al. "Poisoning Effects of Alkali and Alkaline Earth Metal Doping on Selective Catalytic Reduction of NO with NH3 over the Nb-Ce/Zr-PILC Catalysts" . | CATALYSTS 11 . 3 (2021) . |
| APA | Li, Chenxi , Cheng, Jin , Ye, Qing , Meng, Fanwei , Wang, Xinpeng , Dai, Hongxing . Poisoning Effects of Alkali and Alkaline Earth Metal Doping on Selective Catalytic Reduction of NO with NH3 over the Nb-Ce/Zr-PILC Catalysts . | CATALYSTS , 2021 , 11 (3) . |
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