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学者姓名：康天放
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Abstract ：
利用核壳型的CdSe@CdS量子点作为发光物质，并用壳聚糖（CS）、类石墨烯氮化碳（gC_3N_4）与CdSe@CdS量子点合成了CdSe@CdS/CS/gC_3N_4复合物，将该复合物修饰至玻碳电极（GCE）表面，将适配体（Apt）的互补DNA链（cDNA）通过化学反应连接到量子点上，Apt与cDNA发生杂交反应而被修饰至电极表面。将辣根过氧化物酶（HRP）固定到该修饰电极表面，构建了检测卡那霉素（Kana）的电化学发光（ECL）适配体传感器。通过生物催化沉淀（BCP）方法实现Kana的检测，溶液中无Kana时，在H_2O_2的存在下，修饰在电极上的HRP可以催化氧化4-氯-1-萘酚（4-CN），在电极表面产生不导电的苯并-4-氯己二烯酮沉淀，导致电化学发光信号明显降低。溶液中存在Kana时，Kana会与Apt特异性结合，部分dsDNA解旋，导致部分HRP从电极表面脱落，BCP反应减弱，导致ECL信号增强，实现目标物质的特异性检测。计算适配体传感器在Kana溶液中的ECL强度（I）与传感器在空白溶液中的ECL强度（I_0）的差值ΔI (I-I_0)，并以此作为响应信号。结果显示，ΔI与Kana浓度的对数值在1.0×10~(-8)～1.0×10~(-4) g/L范围呈良好的线性关系，检出限为5 ng/L。该传感器在实际样品测定中具有较好的应用前景。
Keyword ：
电化学发光 电化学发光 卡那霉素 卡那霉素 量子点 量子点 适配体 适配体 生物催化沉淀 生物催化沉淀
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| GB/T 7714 | 高会莲 , 康天放 , 鲁理平 et al. 基于CdSe@CdS/壳聚糖/gC_3N_4复合物的卡那霉素电化学发光适配体传感器 [J]. | 分析试验室 , 2023 , 42 (03) : 305-311 . |
| MLA | 高会莲 et al. "基于CdSe@CdS/壳聚糖/gC_3N_4复合物的卡那霉素电化学发光适配体传感器" . | 分析试验室 42 . 03 (2023) : 305-311 . |
| APA | 高会莲 , 康天放 , 鲁理平 , 程水源 . 基于CdSe@CdS/壳聚糖/gC_3N_4复合物的卡那霉素电化学发光适配体传感器 . | 分析试验室 , 2023 , 42 (03) , 305-311 . |
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Abstract ：
制备了硫化镉量子点-壳聚糖(CdS-CS)复合物修饰的玻碳电极(GCE),记作CdS-CS/GCE.以卡那霉素为模板分子,3-氨基苯硼酸(APBA)为功能单体,采用循环伏安法在CdS-CS/GCE表面电聚合得到了分子印迹聚合物(MIP)膜,所制备的传感器记作MIP/CdS-CS/GCE.卡那霉素可与传感器表面的MIP特异性结合,占据印迹孔穴,阻断共反应剂K2 S2 O8扩散到电极表面的通路,使电化学发光强度减弱.以传感器在空白溶液中的电化学发光强度(I0)与传感器在卡那霉素标准溶液中的电化学发光强度(I)的差值ΔI(ΔI=I0-I)作为响应信号,在优化的试验条件下,响应信号ΔI与卡那霉素浓度的对数值在1.0×10-11～1.0×10-7 mol·L-1内呈线性关系,相关系数为0.9990,检出限(3S/N)为5×10-12 mol·L-1.按标准加入法对实际样品进行回收试验,回收率为99.9％～103％,测定值的相对标准偏差(n=5)为2.5％～4.3％.
Keyword ：
分子印迹聚合物 分子印迹聚合物 传感器 传感器 卡那霉素 卡那霉素 电化学发光法 电化学发光法 CdS-CS复合物 CdS-CS复合物
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| GB/T 7714 | 孙晨阳 , 康天放 , 鲁理平 et al. 分子印迹电化学发光传感器的制备及其对卡那霉素的测定应用 [J]. | 理化检验（化学分册） , 2023 , 59 (3) : 249-256 . |
| MLA | 孙晨阳 et al. "分子印迹电化学发光传感器的制备及其对卡那霉素的测定应用" . | 理化检验（化学分册） 59 . 3 (2023) : 249-256 . |
| APA | 孙晨阳 , 康天放 , 鲁理平 , 程水源 . 分子印迹电化学发光传感器的制备及其对卡那霉素的测定应用 . | 理化检验（化学分册） , 2023 , 59 (3) , 249-256 . |
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Abstract ：
本文将多壁碳纳米管(MWCNT)修饰到玻碳电极(GCE)界面,并基于臭氧(O3)与靛蓝三磺酸钾(ITS)的灵敏反应,间接实现了水中O3的定量测定.利用扫描电镜和循环伏安法对该修饰电极进行了形貌和电化学性质表征.在最优实验条件下,溶液中ITS的方波伏安(SWV)峰电流在2.0× 10-7～6.4×10-5 mol·L-1浓度范围内随ITS的浓度增大而呈线性增强,检测限为5×10-8mol·L-1.当体系中存在O3时,ITS的SWV峰电流随臭氧浓度的增加而减小,往ITS溶液中加入臭氧溶液前后峰电流减小的差值与O3浓度的对数值在5.0×10-9～1.0×10 5 mol·L-1范围内呈线性关系,检测限为1×10-9 mol·L-1,本方法具有灵敏度高,操作简便,重现性好的优点.
Keyword ：
靛蓝三磺酸钾 靛蓝三磺酸钾 传感器 传感器 方波伏安法 方波伏安法 臭氧 臭氧 多壁碳纳米管 多壁碳纳米管
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| GB/T 7714 | 晚豪 , 康天放 , 鲁理平 . 基于多壁碳纳米管修饰电极的臭氧传感器研究 [J]. | 化学研究与应用 , 2023 , 35 (11) : 2635-2642 . |
| MLA | 晚豪 et al. "基于多壁碳纳米管修饰电极的臭氧传感器研究" . | 化学研究与应用 35 . 11 (2023) : 2635-2642 . |
| APA | 晚豪 , 康天放 , 鲁理平 . 基于多壁碳纳米管修饰电极的臭氧传感器研究 . | 化学研究与应用 , 2023 , 35 (11) , 2635-2642 . |
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Abstract ：
以京津冀地区BVOCs排放清单为基础,采用WRF-CMAQ模型模拟与情景分析相结合的方式研究了2018年7月京津冀地区BVOCs排放对O_3和PM_(2.5)浓度贡献,解析了北京、邯郸、承德、保定等典型城市不同植被类型BVOCs排放对O_3和SOA浓度的影响水平,并应用O_3和SOA生成潜势核算结果对模拟结果进行验证.结果显示,BVOCs排放对北京、邯郸、承德、保定O_3生成贡献率分别为30.19%、24.77%、35.56%、26.73%,对SOA生成贡献率为2.55%、3.32%、4.17%、3.59%;北京、承德的乔木与果园BVOCs排放对O_3和SOA浓度贡献最大,邯郸、保定的草地与庄稼BVOCs排放对O_3和SOA浓度贡献最大;数值模拟结果与O_3、SOA生成潜势表征的潜在影响基本符合.
Keyword ：
BVOCs BVOCs 植被功能类型 植被功能类型 WRF-CMAQ WRF-CMAQ 生成潜势 生成潜势 O_3和SOA O_3和SOA
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| GB/T 7714 | 蔡斌 , 程昊淼 , 亓浩雲 et al. 京津冀植被类型对典型城市夏季O_3和PM_(2.5)贡献 [J]. | 中国环境科学 , 2023 , 43 (06) : 2734-2743 . |
| MLA | 蔡斌 et al. "京津冀植被类型对典型城市夏季O_3和PM_(2.5)贡献" . | 中国环境科学 43 . 06 (2023) : 2734-2743 . |
| APA | 蔡斌 , 程昊淼 , 亓浩雲 , 李奥哲 , 康天放 . 京津冀植被类型对典型城市夏季O_3和PM_(2.5)贡献 . | 中国环境科学 , 2023 , 43 (06) , 2734-2743 . |
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Abstract ：
本文合成了La~(3+)掺杂的CdS量子点(CdS:La QDs),以其作为发光材料。将量子点吸附于玻碳电极(GCE)表面。采用卡那霉素(Kana)的适配体(apt)及其互补链(cDNA)制备传感器，使apt与cDNA在电极表面杂交形成双链DNA(dsDNA),然后用氯化血红素(hemin)溶液孵育该修饰电极，使hemin嵌入至dsDNA中，制得Kana电化学发光适配体传感器，记作hemin-dsDNA/CdS:La/GCE。建立了简便、灵敏的检测Kana的电化学发光(ECL)方法，当不存在Kana时，电极表面的hemin作为模拟过氧化物酶会催化溶液中的H_2O_2还原为OH~-,使作为量子点...
Keyword ：
La~(3+)离子 La~(3+)离子 CdS量子点 CdS量子点 适配体传感器 适配体传感器 电化学发光 电化学发光 卡那霉素 卡那霉素
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| GB/T 7714 | 高会莲 , 康天放 , 鲁理平 et al. La~(3+)掺杂CdS 量子点的卡那霉素电化学发光适配体传感器研究 [J]. | 化学研究与应用 , 2022 , 34 (03) : 525-532 . |
| MLA | 高会莲 et al. "La~(3+)掺杂CdS 量子点的卡那霉素电化学发光适配体传感器研究" . | 化学研究与应用 34 . 03 (2022) : 525-532 . |
| APA | 高会莲 , 康天放 , 鲁理平 , 程水源 . La~(3+)掺杂CdS 量子点的卡那霉素电化学发光适配体传感器研究 . | 化学研究与应用 , 2022 , 34 (03) , 525-532 . |
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Abstract ：
Air pollution has a serious fallout on human health, and the influences of the different urban morphological characteristics on air pollutants cannot be ignored. In this study, the relationship between urban morphology and air quality (wind speed, CO, and PM2.5) in residential neighborhoods at the meso-microscale was investigated. The changes in the microclimate and pollutant diffusion distribution in the neighborhood under diverse weather conditions were simulated by Computational Fluid Dynamics (CFD). This study identified five key urban morphological parameters (Building Density, Average Building Height, Standard Deviation of Building Height, Mean Building Volume, and Degree of Enclosure) which significantly impacted the diffusion and distribution of pollutants in the neighborhood. The findings of this study suggested that three specific strategies (e.g. volume of a single building should be reduced, DE should be increased) and one comprehensive strategy (the width and height of the single building should be reduced while the number of single buildings should be increased) could be illustrated as an optimized approach of urban planning to relief the air pollution. The result of the combined effects could provide a reference for mitigating air pollution in sustainable urban environments. © 2021
Keyword ：
Wind Wind Air quality Air quality Diffusion Diffusion Computational fluid dynamics Computational fluid dynamics Urban planning Urban planning Buildings Buildings
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| GB/T 7714 | Jiang, Zhiwen , Cheng, Haomiao , Zhang, Peihao et al. Influence of urban morphological parameters on the distribution and diffusion of air pollutants: A case study in China [J]. | Journal of Environmental Sciences (China) , 2021 , 105 : 163-172 . |
| MLA | Jiang, Zhiwen et al. "Influence of urban morphological parameters on the distribution and diffusion of air pollutants: A case study in China" . | Journal of Environmental Sciences (China) 105 (2021) : 163-172 . |
| APA | Jiang, Zhiwen , Cheng, Haomiao , Zhang, Peihao , Kang, Tianfang . Influence of urban morphological parameters on the distribution and diffusion of air pollutants: A case study in China . | Journal of Environmental Sciences (China) , 2021 , 105 , 163-172 . |
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Abstract ：
制备了金纳米粒子-氧化石墨烯(AuNPs-GO)复合物,采用透射电镜(TEM)和紫外-可见吸收光谱(UV-Vis)对其进行了表征。将此复合物修饰到玻碳电极(GCE)表面,再通过Au—S键将巯基修饰的富含鸟嘌呤的DNA链(T30695)自组装到电极表面的金纳米粒子上。T30695可与Pb~(2+)结合形成稳定的平行G-四链体,此G-四链体再与氯化血红素(Hemin)结合形成具有过氧化物酶活性的DNA酶(DNAzyme),基于此制得Pb~(2+)敏感的DNA酶电化学传感器。形成的DNA酶可催化H_2O_2氧化对苯二酚(HQ),实现电化学信号的放大和Pb~(2+)的高灵敏检测。在优化的实验条件下,在...
Keyword ：
DNA酶 DNA酶 方波伏安法 方波伏安法 铅离子(Ⅱ) 铅离子(Ⅱ) 传感器 传感器
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| GB/T 7714 | 杨瑞 , 康天放 , 鲁理平 et al. 基于DNA酶/AuNPs-GO传感器方波伏安法高灵敏检测Pb~(2+) [J]. | 分析化学 , 2021 , 49 (02) : 309-317 . |
| MLA | 杨瑞 et al. "基于DNA酶/AuNPs-GO传感器方波伏安法高灵敏检测Pb~(2+)" . | 分析化学 49 . 02 (2021) : 309-317 . |
| APA | 杨瑞 , 康天放 , 鲁理平 , 叶青 . 基于DNA酶/AuNPs-GO传感器方波伏安法高灵敏检测Pb~(2+) . | 分析化学 , 2021 , 49 (02) , 309-317 . |
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Abstract ：
The sodium-treated sepiolite (NaSep)-supported rare earth oxide (RE/NaSep; RE = La, Eu, Dy, and Tm) samples were prepared using the rotary evaporation method. Physicochemical properties of these materials were characterized by XRD, SEM, BET, FTIR, XPS, H-2-TPR, NH3-TPD, and in situ DRIFTS, and their catalytic activities for formaldehyde (HCHO) (2000 ppm) oxidation were evaluated. The results show that loading of the rare earth oxide on NaSep improved its catalytic performance. Among all the samples, Eu/NaSep performed the best, and complete HCHO conversion was achieved at a temperature of 150 degrees C and a gas hourly space velocity of 240,000 mL/(g h); a good catalytic activity was still maintained after 45 h of stability test. The catalytic oxidation mechanism of HCHO was studied using the in situ DRIFTS technique. As a result, the effective and stable catalytic performance of the Eu/NaSep sample was mainly due to the presence of hydroxyl groups on the sepiolite surface and the doped rare earth oxides, which contributed to its high performance. HCHO oxidation underwent via the steps of HCHO + O-2 -> HCOO- + OH- -> H2O + CO2. It is concluded that the optimal catalytic activity of Eu/NaSep was associated with the highest O-ads/O-latt atomic ratio, the largest amount of hydroxyl groups, the highest acidity, and the best reducibility. The present work may provide new insights into the application in the removal of high-concentration HCHO over the rare earth oxides supported on natural low-cost clays.
Keyword ：
rare earth oxide rare earth oxide HCHO oxidation HCHO oxidation volatile organic compound volatile organic compound sodium-treated sepiolite sodium-treated sepiolite
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| GB/T 7714 | Dong, Ning , Ye, Qing , Chen, Mengyue et al. Catalytic Oxidation of HCHO over the Sodium-Treated Sepiolite-Supported Rare Earth (La, Eu, Dy, and Tm) Oxide Catalysts [J]. | CATALYSTS , 2020 , 10 (3) . |
| MLA | Dong, Ning et al. "Catalytic Oxidation of HCHO over the Sodium-Treated Sepiolite-Supported Rare Earth (La, Eu, Dy, and Tm) Oxide Catalysts" . | CATALYSTS 10 . 3 (2020) . |
| APA | Dong, Ning , Ye, Qing , Chen, Mengyue , Cheng, Shuiyuan , Kang, Tianfang , Dai, Hongxing . Catalytic Oxidation of HCHO over the Sodium-Treated Sepiolite-Supported Rare Earth (La, Eu, Dy, and Tm) Oxide Catalysts . | CATALYSTS , 2020 , 10 (3) . |
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In this study, a novel electrochemiluminescence (ECL) biosensor based on a CdSe@CdS quantum dot (QD)-functionalized MoS2-modified electrode was developed for the sensitive detection of mercury ions. Polycationic poly(diallyldimethylammonium chloride) (PDDA) and negatively charged QDs were adsorbed on the surface of MoS2, in sequence, to form the QD-PDDA-MoS2 composites, which were employed as matrices for immobilizing thymine-rich DNA sequences (DNA(1)). The gold nanoparticles (AuNPs) were combined with another type of thymine-rich DNA sequences (DNA(2)) and glucose oxidase (GOD) to prepare the GOD-AuNP-DNA(2) conjugates. The composites were characterized via UV-visible absorption spectroscopy, fluorescence and transmission electron microscopy. A thymine-Hg2+-thymine complex was formed through Hg2+ mismatching with DNA(1) and DNA(2). GOD was, therefore, modified onto the electrode surface. GOD catalyzed the reduction of dissolved oxygen by glucose to produce hydrogen peroxide, which was a co-reactant of the QDs. The electrochemiluminescence signal of the biosensor increased linearly with the increase in the Hg2+ concentration over the range from 1.0 x 10(-12) to 1.0 x 10(-6) M with a detection limit of 1 x 10(-13) M. The reproducibility, stability and specificity of the biosensor was also studied. The biosensor was used to determine Hg2+ in a real water sample and satisfactory results were obtained.
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| GB/T 7714 | He, Zhang-Jin , Kang, Tian-Fang , Lu, Li-Ping et al. An electrochemiluminescence sensor based on CdSe@CdS-functionalized MoS2 and a GOD-labeled DNA probe for the sensitive detection of Hg(ii) [J]. | ANALYTICAL METHODS , 2020 , 12 (4) : 491-498 . |
| MLA | He, Zhang-Jin et al. "An electrochemiluminescence sensor based on CdSe@CdS-functionalized MoS2 and a GOD-labeled DNA probe for the sensitive detection of Hg(ii)" . | ANALYTICAL METHODS 12 . 4 (2020) : 491-498 . |
| APA | He, Zhang-Jin , Kang, Tian-Fang , Lu, Li-Ping , Cheng, Shui-Yuan . An electrochemiluminescence sensor based on CdSe@CdS-functionalized MoS2 and a GOD-labeled DNA probe for the sensitive detection of Hg(ii) . | ANALYTICAL METHODS , 2020 , 12 (4) , 491-498 . |
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The alkali metal (M = Na, K, Rb, and Cs)-modified C-FDU-15 (M-C-FDU-15(x); x was the M/C-FDU-15 M ratio, and equal to 0.01-0.03) samples were prepared through an in situ process, and characterized by means of the TG, XRD, TEM, EDS, N-2 adsorption-desorption, O-2-TPD, and CO2-TPD techniques. The (NO + O-2) adsorption mechanism was investigated using the (NO + O-2)-TPD and DRIFTS techniques. The results show that the sequence of (NO + O-2) adsorption performance was Na-C-FDU-15(0.01) (104. 1 mg/g) > K-C-FDU-15(0.01) (92.4 mg/g) > C-FDU-15 (76.2 mg/g) > Rb-C-FDU-15(0.01) (65.1 mg/g) > Cs-C-FDU-15(0.01) (62.3 mg/g). The alkali metal was uniformly distributed in C-FDU-15 and its doping enhanced the amount of the basic sites in the sample. Moreover, the optimal Na/C-FDU-15 M ratio was 0.02. (NO + O-2) were chemically adsorbed mainly in the forms of nitrite (NO2) and nitrate (NO3) on M-C-FDU-15(x). A more amount of NO was converted to nitrate than to nitrite. There were three key factors of enhancing the (NO + O-2) adsorption capacity of C-FDU-15 due to alkali metal doping: the first factor was the increasing of surface area and pore volume of the sample, the second one was the enhancement in amount of the active sites in the sample, and the third one was the smaller alkali metal ionic radius in the sample. (C) 2020 Elsevier Inc. All rights reserved.
Keyword ：
Adsorption mechanism Adsorption mechanism NO adsorption NO adsorption O-2 adsorption O-2 adsorption Kinetics Kinetics Alkali metal doping Alkali metal doping Mesoporous C-FDU-15 Mesoporous C-FDU-15
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| GB/T 7714 | Wu, Runping , Ye, Qing , Wu, Kai et al. Alkali metal-modified C-FDU-15: Highly efficient adsorbents for adsorption of NO and O-2 at low temperatures [J]. | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2020 , 577 : 217-232 . |
| MLA | Wu, Runping et al. "Alkali metal-modified C-FDU-15: Highly efficient adsorbents for adsorption of NO and O-2 at low temperatures" . | JOURNAL OF COLLOID AND INTERFACE SCIENCE 577 (2020) : 217-232 . |
| APA | Wu, Runping , Ye, Qing , Wu, Kai , Cheng, Shuiyuan , Kang, Tianfang , Dai, Hongxing . Alkali metal-modified C-FDU-15: Highly efficient adsorbents for adsorption of NO and O-2 at low temperatures . | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2020 , 577 , 217-232 . |
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