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Author:

Liu, W. Q. (Liu, W. Q..) (Scholars:刘卫强) | Cui, Z. Z. (Cui, Z. Z..) | Wang, G. P. (Wang, G. P..) | Zhang, D. T. (Zhang, D. T..) (Scholars:张东涛) | Yue, M. (Yue, M..) (Scholars:岳明) | Zhang, J. X. (Zhang, J. X..)

Indexed by:

EI Scopus SCIE

Abstract:

Static state immersion experiments, polarisation curve and electrochemical impedance spectroscopy tests have been applied to investigate the corrosion kinetics for both spark plasma sintered (SPS) and conventional sintered Nd-Fe-B magnets in NaCl electrolyte. Effect of microstructure modification on their chemical stability of the magnets was discussed. The electrochemical reactions of both magnets are controlled by the step of active substances adsorption process at the open circuit potential and the anodic potential, which turn to diffusion process at the cathodal potential. Although both magnets are susceptible to corrosion in saline electrolytes, SPS magnets are more corrosion resistant than conventional sintered magnets due to their special microstructure that is different from those of conventional sintered magnets. In SPS magnets, the grain size of the Nd(2)Fe(14)B main phase is fine and uniform, only a few Nd rich phase form along the grain boundaries of Nd(2)Fe(14)B phase, while most of them agglomerate into triple junctions as small particles. Such microstructure effectively restrains the aggressive intergranular corrosion along Nd rich phases. As a result, the SPS magnet possesses excellent corrosion resistance in NaCl electrolyte.

Keyword:

Nd-Fe-B permanent magnets Spark plasma sintering Microstructure modification Corrosion kinetics

Author Community:

  • [ 1 ] [Liu, W. Q.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Cui, Z. Z.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Zhang, D. T.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Yue, M.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang, J. X.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Wang, G. P.]Jiangxi Normal Univ, Coll Phys & Commun Elect, Nanchang 330022, Peoples R China

Reprint Author's Address:

  • 岳明

    [Yue, M.]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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Source :

CORROSION ENGINEERING SCIENCE AND TECHNOLOGY

ISSN: 1478-422X

Year: 2011

Issue: 5

Volume: 46

Page: 667-670

1 . 8 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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