The　low　intrinsic　activity　of　Fe/N/C　oxygen　catalysts　restricts　their　commercial　application　in　the　fuel　cells　technique;　herein,　we　demonstrated　the　interface　engineering　of　plasmonic　induced　Fe/N/C-F　catalyst　with　primarily　enhanced　oxygen　reduction　performance　for　fuel　cells　applications.　The　strong　interaction　between　F　and　Fe-N-4　active　sites　modifies　the　catalyst　interfacial　properties　as　revealed　by　X-ray　absorption　structure　spectrum　and　density　functional　theory　calculations,　which　changes　the　electronic　structure　of　Fe-N　active　site　resulting　from　more　atoms　around　the　active　site　participating　in　the　reaction　as　well　as　super-hydrophobicity　from　C-F　covalent　bond.　The　hybrid　contribution　from　active　sites　and　carbon　support　is　proposed　to　optimize　the　three-phase　microenvironment　efficiently　in　the　catalysis　electrode,　thereby　facilitating　efficient　oxygen　reduction　performance.　High　catalytic　performance　for　oxygen　reduction　and　fuel　cells　practical　application　catalyzed　by　Fe/N/C-F　catalyst　is　thus　verified,　which　offers　a　novel　catalyst　system　for　fuel　cells　technique.