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Abstract：
Two dipalladium complexes [(bpy)(2)Pd-2(NO3)(2)](NO3)(2), [(dmbpy)(2)Pd-2(NO3)(2)](NO3)(2) (bpy=2,2-bipyridine, dmbpy=4,4＇ -dimethyl-2,2-bipyridine) were used as＂clips＂to coordinate with ditopic pyrazolate ligands (HL1, HL2), leading to the formation of [Pd2L2](2-) -type dinuclear coordination＂clips＂with strong intramolecular Pd(II)center dot center dot center dot Pd(II) bonding interaction through a spontaneous deprotonation of the pyrazole ligands in aqueous solution. Such well-defined complexes C1 similar to C4 have been characterized by single-crystal X-ray diffraction analysis, elemental analysis, H-1 and C-13 NMR, electrospray ionization mass spectrometry (ESI-MS) and IR spectroscopy. Furthermore, all these clip-like dipalladium(II) complexes exhibited highly catalytic activities towards Suzuki-coupling reaction under mild conditions. CCDC: 2060495, C1 center dot 2NO(3)(-).
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CHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN： 1001-4861
Year： 2021
Issue： 8
Volume： 37
Page： 1493-1503
0 . 7 0 0
JCR@2022
ESI Discipline： CHEMISTRY;
ESI HC Threshold：96
JCR Journal Grade：4
Cited Count：
WoS CC Cited Count： 0
SCOPUS Cited Count：
ESI Highly Cited Papers on the List： 0 Unfold All
WanFang Cited Count：
Chinese Cited Count：
30 Days PV： 17
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