The　micro-nanoscale　AlSb　precipitates　are　introduced　into　selected　commercial　aluminum　alloys　as　anode　material　for　alkaline　Al-air　battery,　and　their　corrosion　behaviors,　microstructure　and　discharge　properties　are　investigated　in　details.　It　is　found　that　such　Sb　addition　can　coexist　in　harmonization　with　already　added　other　alloying　elements　in　the　Al　alloys,　and　further　bring　out　the　improved　microstructure　and　the　electrochemical　performance　as　the　Al　anodes.　The　energy　density　of　1080　alloy　with　Sb　(1544　Wh.kg(-1))　is　30.9%　higher　than　that　without　Sb　at　10　mA.cm(-2).　The　resulting　electrochemical　impedance　spectroscopy　(EIS)　with　Sb　addition　demonstrates　that　the　diffusion　resistance　(RC)　and　inductance　(L)　reduce　with　decreasing　thickness　of　passive　film　on　the　anode　surface　while　increasing　its　discharge　voltage.　The　improved　refinement　in　microstructure　can　also　restrain　hydrogen　evolution　from　the　Al-based　anode.　The　fundamental　information　obtained　is　useful　for　designing　and　fabricating　the　Al　anode　products　from　low-cost　commercial　alloys　with　added-on　electrochemical　performance.