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Author:

Deng, J. (Deng, J..) | Lu, H. (Lu, H..) | Xu, B. (Xu, B..) | Cao, Y. (Cao, Y..) | Yang, W. (Yang, W..) | Liu, J. (Liu, J..)

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Scopus

Abstract:

To date, research on air battery catalysts has been mainly focused on finding materials with a high oxygen reduction reaction (ORR) catalytic activity. However, the high cost of platinum catalysts restricts their commercialization. Herein, we report a simple hydrothermal-calcination method to fabricate low-cost NiMn2O4 -based Ni-Mn bimetallic oxides. The Ni-Mn-600 sample showed a high onset potential (1.01 V vs. RHE), which was more positive than that for 20 wt% Pt/C (0.97 V vs. RHE), and its half-wave potential (0.78 V vs. RHE) was comparable to that for 20 wt% Pt/C (0.84 V vs. RHE). Moreover, Ni-Mn-600 as an Al-air battery air–cathode catalyst exhibited a high discharge plateau of 1.42 V and peak power density of 100.45 mW cm−2, which outperformed those for 20 wt% Pt/C (1.34 V and 76.10 mW cm−2). The high ORR electrocatalytic activity of Ni-Mn-600 may be attributed to the nanorod morphology and high ratio of (Mn3++Mn4+)/Mn2+ and Ni3+/Ni2+. This work demonstrated that NiMn2O4-based Ni-Mn bimetallic oxides as cathode catalysts have good research prospects in aluminum-air batteries and other energy applications. © 2020 Elsevier B.V.

Keyword:

Al-air battery Oxygen reduction reaction NiMn2O4-based Ni-Mn bimetallic oxides

Author Community:

  • [ 1 ] [Deng J.]School of Materials Science and Engineering, Beihang University, Beijing, 100191, China
  • [ 2 ] [Lu H.]School of Materials Science and Engineering, Beihang University, Beijing, 100191, China
  • [ 3 ] [Xu B.]School of Materials Science and Engineering, Beihang University, Beijing, 100191, China
  • [ 4 ] [Xu B.]Device Mechanism Research Institute, Beijing BOE sensor Technology Co., Ltd., Beijing, 100176, China
  • [ 5 ] [Cao Y.]School of Materials Science and Engineering, Beihang University, Beijing, 100191, China
  • [ 6 ] [Cao Y.]School of Energy and Power Engineering, Beihang University, Beijing, 100191, China
  • [ 7 ] [Yang W.]School of Materials Science and Engineering, Beihang University, Beijing, 100191, China
  • [ 8 ] [Yang W.]School of Basic Education, Beijing Polytechnic College, Beijing, 100142, China
  • [ 9 ] [Liu J.]School of Materials Science and Engineering, Beihang University, Beijing, 100191, China

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Source :

Chemical Engineering Journal

ISSN: 1385-8947

Year: 2021

Volume: 413

1 5 . 1 0 0

JCR@2022

ESI Discipline: ENGINEERING;

ESI HC Threshold:87

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 25

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 12

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