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Abstract:
Optical feedback for either the excitation or the signal is an effective approach to enhance the detection sensitivity of Raman scattering spectroscopy. A combination of plasmonic and optical feedback schemes may supply multifold enhancement mechanisms with further improved efficiency. Herein, a plasmonic Bragg grating (PBG) consisting of periodically distributed silver nanoslabs coated onto the sidewalls of the grating lines is reported. Localized surface plasmons excited in the silver nanoslabs with a large width/thickness ratio facilitate enhanced local field and Raman interaction. Asymmetric Bragg diffraction not only supplies optical feedback along the grating plane to extend largely the laser-molecule interaction distance but also enables efficient collection of the Raman signal through back-diffraction into the detection system. Such a design accomplishes "volume" surface-enhanced Raman scattering with a modulation depth of more than 500 nm and strong optical feedback, extending largely the limited interaction distance of surface plasmons. With respect to the scheme using Ag films for enhancement, a further enhancement factor larger than 2.8 x 10(3) has been achieved by the PBG device in the direct detection of the low-concentration water solution of R6G molecules. The discovered photophysics is potentially important for practical applications in in situ water pollutant detection.
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ADVANCED ENGINEERING MATERIALS
ISSN: 1438-1656
Year: 2021
Issue: 6
Volume: 24
3 . 6 0 0
JCR@2022
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:116
JCR Journal Grade:2
Cited Count:
WoS CC Cited Count: 1
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 7
Affiliated Colleges: