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Author:

Liu, Miao (Liu, Miao.) | Zhang, Xinping (Zhang, Xinping.) (Scholars:张新平) | Mu, Yunyun (Mu, Yunyun.) | Zhao, Zhi (Zhao, Zhi.) | Fu, Yulan (Fu, Yulan.) | Liu, Feifei (Liu, Feifei.) | Li, Jiajun (Li, Jiajun.) | Liu, Yue (Liu, Yue.) | Hu, Jingyun (Hu, Jingyun.) | Song, Xiaoyan (Song, Xiaoyan.)

Indexed by:

EI Scopus SCIE

Abstract:

Optical feedback for either the excitation or the signal is an effective approach to enhance the detection sensitivity of Raman scattering spectroscopy. A combination of plasmonic and optical feedback schemes may supply multifold enhancement mechanisms with further improved efficiency. Herein, a plasmonic Bragg grating (PBG) consisting of periodically distributed silver nanoslabs coated onto the sidewalls of the grating lines is reported. Localized surface plasmons excited in the silver nanoslabs with a large width/thickness ratio facilitate enhanced local field and Raman interaction. Asymmetric Bragg diffraction not only supplies optical feedback along the grating plane to extend largely the laser-molecule interaction distance but also enables efficient collection of the Raman signal through back-diffraction into the detection system. Such a design accomplishes "volume" surface-enhanced Raman scattering with a modulation depth of more than 500 nm and strong optical feedback, extending largely the limited interaction distance of surface plasmons. With respect to the scheme using Ag films for enhancement, a further enhancement factor larger than 2.8 x 10(3) has been achieved by the PBG device in the direct detection of the low-concentration water solution of R6G molecules. The discovered photophysics is potentially important for practical applications in in situ water pollutant detection.

Keyword:

enhancement factor silver nanoslabs Raman spectroscopy plasmonic Bragg grating localized surface plasmon optical feedback

Author Community:

  • [ 1 ] [Liu, Miao]Beijing Univ Technol, Fac Sci, Inst Informat Photon Technol, Beijing 100124, Peoples R China
  • [ 2 ] [Zhang, Xinping]Beijing Univ Technol, Fac Sci, Inst Informat Photon Technol, Beijing 100124, Peoples R China
  • [ 3 ] [Mu, Yunyun]Beijing Univ Technol, Fac Sci, Inst Informat Photon Technol, Beijing 100124, Peoples R China
  • [ 4 ] [Fu, Yulan]Beijing Univ Technol, Fac Sci, Inst Informat Photon Technol, Beijing 100124, Peoples R China
  • [ 5 ] [Li, Jiajun]Beijing Univ Technol, Fac Sci, Inst Informat Photon Technol, Beijing 100124, Peoples R China
  • [ 6 ] [Liu, Yue]Beijing Univ Technol, Fac Sci, Inst Informat Photon Technol, Beijing 100124, Peoples R China
  • [ 7 ] [Hu, Jingyun]Beijing Univ Technol, Fac Sci, Inst Informat Photon Technol, Beijing 100124, Peoples R China
  • [ 8 ] [Zhao, Zhi]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 9 ] [Song, Xiaoyan]Beijing Univ Technol, Coll Mat Sci & Engn, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 10 ] [Liu, Feifei]Tianjin Normal Univ, Coll Phys & Mat Sci, Tianjin 300387, Peoples R China

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Source :

ADVANCED ENGINEERING MATERIALS

ISSN: 1438-1656

Year: 2021

Issue: 6

Volume: 24

3 . 6 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:116

JCR Journal Grade:2

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 7

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