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Author:

Liu, Shuang (Liu, Shuang.) | Ma, Limin (Ma, Limin.) | Zhen, Cheng (Zhen, Cheng.) | Wang, Yishu (Wang, Yishu.) | Li, Dan (Li, Dan.) | Guo, Fu (Guo, Fu.) (Scholars:郭福)

Indexed by:

EI Scopus SCIE

Abstract:

Crystalline and amorphous cobalt-phosphorus (Co-P) coatings have their own advantages in interfacial dif-fusion resistance and mechanical ductility of solder joints, respectively, but it cannot be better at both. In this work, the hybrid crystalline-amorphous Co-P coating (Co-9.1 at.% P) was fabricated and applied on the Cu/Sn interface by controlling the crystallinity through compositional design. Combining the advan-tages of crystalline and amorphous Co-P, strategies for solder joints with high shear strength, ductile inter -metallic compounds (IMCs) and slow interface consumption was proposed. The evolution, microstructure, phase, and mechanical properties of the Co-Sn, Co-Sn-P and P-rich layers in solid-state diffusion were sys-tematically characterized and tested by means of SEM, EPMA, EBSD, TEM, nanoindentation, and shear test. It was found that the hybrid Co-P coating achieved a low consumption rate, 14.2 nm/h, attributing to the par-tially crystalline structure and the Co-Sn-P exfoliation behavior. In addition, solder joints containing large -thickness ductile Co-Sn IMCs, 3.2-3.6 GPa of hardness, was established. The shear strength after aging reached 75.4 MPa relying on the large thickness of Co-Sn IMCs. Severe mechanical loads would be able to be withstand by virtue of the plastic deformation of ductile IMCs. Hybrid crystalline-amorphous Co-P would be a promising interface material in microelectronic packaging.(c) 2022 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Keyword:

Intermetallic compound Hybrid coating Ductility Exfoliation Diffusion resistance Cobalt-phosphorus

Author Community:

  • [ 1 ] [Liu, Shuang]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 2 ] [Ma, Limin]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 3 ] [Zhen, Cheng]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 4 ] [Wang, Yishu]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 5 ] [Li, Dan]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 6 ] [Guo, Fu]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 7 ] [Liu, Shuang]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 8 ] [Ma, Limin]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 9 ] [Zhen, Cheng]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 10 ] [Wang, Yishu]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 11 ] [Li, Dan]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 12 ] [Guo, Fu]Beijing Univ Technol, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 13 ] [Guo, Fu]Beijing Union Univ, Coll Robot, Beijing 100101, Peoples R China

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Source :

MATERIALS & DESIGN

ISSN: 0264-1275

Year: 2022

Volume: 224

8 . 4

JCR@2022

8 . 4 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:66

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 9

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 7

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