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Author:

Zhang, Zhenghan (Zhang, Zhenghan.) | Li, Yuanli (Li, Yuanli.) | Zhong, Jiaxing (Zhong, Jiaxing.) | Zhang, Hui (Zhang, Hui.) | Gao, Chunlang (Gao, Chunlang.) | Zhuang, Chunqiang (Zhuang, Chunqiang.) (Scholars:庄春强)

Indexed by:

EI Scopus SCIE

Abstract:

Small-sized particles are usually used as cocatalysts and anchored onto a large-sized photocatalyst for fast charge separation. However, the current problem for the design of photocatalysts is that a high loading of small-sized particles leads to full coverage of photocatalysts, resulting in the decrease of hydrogen production. Here, we propose a different way to construct photocatalytic systems. Large-scale carbon nanotubes with doped nitrogen (N-CNTs) are used to couple with TiO2 quantum dots. The H-2 yield for our optimized photocatalytic system is similar to 146 mmol/g. With further considering the light-induced thermal effect, the H-2 yield reaches up to similar to 320.6 mmol/g. Electrochemical and spectroscopic data show that large-sized N-CNTs can offer abundant active sites to realize the rapid carrier separation for tremendously improved hydrogen production.

Keyword:

N-CNTs TiO2 quantum dot photocatalytic H-2 light-thermal effect effective carrier separation

Author Community:

  • [ 1 ] [Zhang, Zhenghan]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Yuanli]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 3 ] [Zhong, Jiaxing]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 4 ] [Gao, Chunlang]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 5 ] [Zhuang, Chunqiang]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 6 ] [Zhang, Hui]Ningxia Univ, State Key Lab High Efficiency Utilizat Coal & Gree, Yinchuan 750021, Peoples R China

Reprint Author's Address:

  • [Zhuang, Chunqiang]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Fac Mat & Mfg, Beijing 100124, Peoples R China;;

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Source :

ACS APPLIED NANO MATERIALS

Year: 2022

Issue: 1

Volume: 6

Page: 453-460

5 . 9

JCR@2022

5 . 9 0 0

JCR@2022

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 11

SCOPUS Cited Count: 13

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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