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Author:

Zhang, Wencong (Zhang, Wencong.) | Li, Fan (Li, Fan.) | Shi, Fenglei (Shi, Fenglei.) | Hu, Hao (Hu, Hao.) | Liang, Jing (Liang, Jing.) | Yang, Haiyan (Yang, Haiyan.) | Ye, Yaoli (Ye, Yaoli.) | Mao, Zhengsong (Mao, Zhengsong.) | Shang, Wen (Shang, Wen.) | Deng, Tao (Deng, Tao.) | Ke, Xiaoxing (Ke, Xiaoxing.) | Wu, Jianbo (Wu, Jianbo.)

Indexed by:

EI Scopus SCIE

Abstract:

Designing shape-controlled Pt-based core-shell nanocrystals is a prospective strategy to maximize the utilization of Pt while maintaining high activity for oxygen reduction reaction (ORR). However, the core-shell structures with ultrathin Pt shell exhibit limited electrochemical durability. Therefore, a thicker shell is proposed to successfully improve the durability of the core-shell structures by preventing the core from dissolution. Never-theless, the deposition of Pt tends to switch to the Stranski-Krastanov (S-K) growth mode with the increase of the number of layer, resulting in the absence of a conformal morphology. Herein, we realize the deposition of three-to-five-layer epitaxial Pt-Co layers on Pd octahedral seeds by introducing tensile strain in the epitaxial layer to impede the S-K growth. The as-obtained Pd@ Pt-Co octahedra with four layers exhibit enhanced mass activity (0.69 A/mgPt) and specific activity (1.00 mA/cm2) for ORR, which are 4.93 and 5 times that of the commercial Pt/C, respectively. Furthermore, it shows only 17% decay for specific activity after a 30,000-cycle durability test. This work is expected to enlighten the design and synthesis of related core-shell nanocrystals with facetted multicomponent shells, offering a promising strategy for designing cost-effective and efficient catalysts.

Keyword:

oxygen reduction reaction tensile strain durability Stranski-Krastanov deposition Pd@Pt-Co octahedra

Author Community:

  • [ 1 ] [Zhang, Wencong]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 2 ] [Li, Fan]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 3 ] [Shi, Fenglei]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 4 ] [Hu, Hao]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 5 ] [Liang, Jing]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 6 ] [Shang, Wen]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 7 ] [Deng, Tao]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 8 ] [Wu, Jianbo]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 9 ] [Ye, Yaoli]Yuchai Synland Technol Co Ltd, Nanning 530007, Peoples R China
  • [ 10 ] [Mao, Zhengsong]Yuchai Synland Technol Co Ltd, Nanning 530007, Peoples R China
  • [ 11 ] [Yang, Haiyan]Shanghai Jiao Tong Univ, Ctr Hydrogen Sci, Shanghai 200240, Peoples R China
  • [ 12 ] [Deng, Tao]Shanghai Jiao Tong Univ, Ctr Hydrogen Sci, Shanghai 200240, Peoples R China
  • [ 13 ] [Ke, Xiaoxing]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 14 ] [Wu, Jianbo]Shanghai Jiao Tong Univ, Zhangjiang Inst Adv Study, Ctr Hydrogen Sci, Future Mat Innovat Ctr, Shanghai 200240, Peoples R China
  • [ 15 ] [Wu, Jianbo]Shanghai Jiao Tong Univ, Mat Genome Initiat Ctr, Shanghai 200240, Peoples R China

Reprint Author's Address:

  • [Wu, Jianbo]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China;;[Ke, Xiaoxing]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China;;[Wu, Jianbo]Shanghai Jiao Tong Univ, Zhangjiang Inst Adv Study, Ctr Hydrogen Sci, Future Mat Innovat Ctr, Shanghai 200240, Peoples R China;;[Wu, Jianbo]Shanghai Jiao Tong Univ, Mat Genome Initiat Ctr, Shanghai 200240, Peoples R China;;

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Source :

ACS APPLIED MATERIALS & INTERFACES

ISSN: 1944-8244

Year: 2023

Issue: 3

Volume: 15

Page: 3993-4000

9 . 5 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:26

Cited Count:

WoS CC Cited Count: 8

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 11

Affiliated Colleges:

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