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Author:

Xie, Jinshu (Xie, Jinshu.) | Zhang, Jinghuai (Zhang, Jinghuai.) | Zhang, Zhi (Zhang, Zhi.) | Yu, Zijian (Yu, Zijian.) | Xu, Zhihao (Xu, Zhihao.) | Wang, Ru (Wang, Ru.) | Fang, Daqing (Fang, Daqing.) | Zhang, Xiaobo (Zhang, Xiaobo.) | Zhang, Xiaoru (Zhang, Xiaoru.) | Wu, Ruizhi (Wu, Ruizhi.)

Indexed by:

EI Scopus SCIE

Abstract:

It is a long-term challenge to further improve the corrosion resistance while ensuring the strength of magnesium (Mg) alloys. Revealing the effect of potential fluctuation on the micro-galvanic corrosion and the subsequent film formation is important for understanding the corrosion mechanism of Mg alloys with multiple strengthening phases/structures. Here, we prepared the high-strength Mg-14.4Er-1.44Zn-0.3Zr (wt.%) alloys containing hybrid structures, i.e., elongated long-period stacking ordered (LPSO) blocks + intragranular stacking faults (SFs)/LPSO lamellae. The Mg alloy with elongated LPSO blocks and intragranular LPSO lamellae (EZ-50 0 alloy) obtains good corrosion resistance (2.2 mm y -1 ), while the Mg alloy containing elongated LPSO blocks and intragranular SFs (EZ-40 0 alloy) shows a significantly higher corrosion rate (6.9 mm y -1 ). The results of scanning Kelvin probe force microscopy (SKPFM) show the elongated LPSO blocks act as cathode phase (87 mV in EZ-40 0 alloy), and the SFs serve as the weak anode (30 mV in EZ-40 0 alloy), resulting in high potential fluctuation in EZ-40 0 alloy. On the contrary, both elongated blocks and intragranular lamellae are cathodic LPSO phase (67-69 mV) in EZ-50 0 alloy, leading to a lower potential fluctuation. Quasi in-situ atomic force microscope (AFM) observation indicates that high potential fluctuation would cause strong micro-galvanic corrosion, and subsequently leads to the failure in rapid formation of corrosion film, finally forming a loose and porous film, while relatively low potential fluctuation could result in more uniform corrosion mode and facilitate the rapid formation of protective film. Therefore, we propose that it is an effective way to develop high-strength corrosionresistant Mg alloys by controlling the potential fluctuation to form a "uniform potential" strengthening microstructure. (c) 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

Keyword:

Stacking faults Corrosion behavior Quasi in-situ AFM LPSO phase SKPFM Mg alloys Potential fluctuation

Author Community:

  • [ 1 ] [Xie, Jinshu]Harbin Engn Univ, Coll Mat Sci & Chem Engn, Key Lab Superlight Mat & Surface Technol, Minist Educ, Harbin 150001, Peoples R China
  • [ 2 ] [Zhang, Jinghuai]Harbin Engn Univ, Coll Mat Sci & Chem Engn, Key Lab Superlight Mat & Surface Technol, Minist Educ, Harbin 150001, Peoples R China
  • [ 3 ] [Zhang, Zhi]Harbin Engn Univ, Coll Mat Sci & Chem Engn, Key Lab Superlight Mat & Surface Technol, Minist Educ, Harbin 150001, Peoples R China
  • [ 4 ] [Xu, Zhihao]Harbin Engn Univ, Coll Mat Sci & Chem Engn, Key Lab Superlight Mat & Surface Technol, Minist Educ, Harbin 150001, Peoples R China
  • [ 5 ] [Wang, Ru]Harbin Engn Univ, Coll Mat Sci & Chem Engn, Key Lab Superlight Mat & Surface Technol, Minist Educ, Harbin 150001, Peoples R China
  • [ 6 ] [Wu, Ruizhi]Harbin Engn Univ, Coll Mat Sci & Chem Engn, Key Lab Superlight Mat & Surface Technol, Minist Educ, Harbin 150001, Peoples R China
  • [ 7 ] [Yu, Zijian]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 8 ] [Fang, Daqing]Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
  • [ 9 ] [Zhang, Xiaoru]Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
  • [ 10 ] [Zhang, Xiaobo]Nanjing Inst Technol, Jiangsu Key Lab Adv Struct Mat & Applicat Technol, Nanjing 211167, Peoples R China

Reprint Author's Address:

  • [Zhang, Jinghuai]Harbin Engn Univ, Coll Mat Sci & Chem Engn, Key Lab Superlight Mat & Surface Technol, Minist Educ, Harbin 150001, Peoples R China;;[Yu, Zijian]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China;;

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Source :

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY

ISSN: 1005-0302

Year: 2023

Volume: 151

Page: 190-203

1 0 . 9 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:26

Cited Count:

WoS CC Cited Count: 39

SCOPUS Cited Count: 44

ESI Highly Cited Papers on the List: 2 Unfold All

  • 2024-5
  • 2024-1

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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