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Abstract:
Micro-galvanic corrosion, driven by potential differences between strengthening phases and the matrix, is a major concern for Mg alloys in NaCl solution. Intriguingly, we find that the micro-galvanic corrosion, dominated by the nobler 18R-LPSO phase, is suppressed in Na2SO4 solution, where both the LPSO and Mg matrix are corroded simultaneously. Since the LPSO phase contains more Er/Zn atoms than matrix, higher proportion of Er3+/Zn2+ could be released in SO42--affected corrosion, eventually forming a more protective corrosion film containing Er2O3/ZnO/ZnS. These findings highlight the specific corrosion behavior of Mg alloys in Na2SO4 solution, offering valuable insights for corrosion mitigation strategies.
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Source :
CORROSION SCIENCE
ISSN: 0010-938X
Year: 2025
Volume: 243
8 . 3 0 0
JCR@2022
Cited Count:
WoS CC Cited Count: 1
SCOPUS Cited Count: 4
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 6
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