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Author:

Tian, Chong (Tian, Chong.) | He, Yong (He, Yong.) | Zhu, Yao-hui (Zhu, Yao-hui.) | Du, Juan (Du, Juan.) | Liu, Shi-ming (Liu, Shi-ming.) | Guo, Wen-hui (Guo, Wen-hui.) | Zhong, Hong-xia (Zhong, Hong-xia.) | Lu, Jing (Lu, Jing.) | Wang, Xinqiang (Wang, Xinqiang.) | Shi, Jun-jie (Shi, Jun-jie.)

Indexed by:

EI Scopus SCIE

Abstract:

Since the prediction of multi-hydrogen high-temperature superconductor by Ashcroft in 2004, many possible candidates have been proposed, e.g., LaH10 showing the highest superconducting transition temperature (T-c) around 250-260 K at 170-200 GPa hitherto. However, this pressure is too large to be taken into practical use. To address this challenge, it proposes a few-hydrogen metal-bonded perovskite superconductor, MgHCu3, by combining a novel design idea with first-principles calculations. Different from multi-hydrogen hydrides, whose high T-c relies on extreme pressure, the metallic bond in few-hydrogen superconductor MgHCu3 improves the structural stability and ductility at atmospheric pressure. Here, the small amount of hydrogen is found to be vital for T-c. After the incorporation of hydrogen, the electron-phonon coupling constant of MgHCu3 is increased to 0.83, which is larger than that of the well-known MgB2. Moreover, the anisotropy of MgHCu3 also plays an important role in enhancing T-c. Based on the Migdal-Eliashberg theory, it predicts that the phonon-mediated metal-bonded perovskite MgHCu3 is a superconductor with T-c of 42 K. The first predicted ternary metal-bonded perovskite, MgHCu3, enriches the family of perovskite and will promote further investigation on few-hydrogen superconductors under atmospheric pressure.

Keyword:

eco-friendly elements few-hydrogen high-temperature superconductor ambient pressure first-principles calculation Migdal-Eliashberg theory

Author Community:

  • [ 1 ] [Tian, Chong]Peking Univ, Sch Phys, Yangtze Delta Inst Optoelect, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 2 ] [He, Yong]Peking Univ, Sch Phys, Yangtze Delta Inst Optoelect, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 3 ] [Liu, Shi-ming]Peking Univ, Sch Phys, Yangtze Delta Inst Optoelect, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 4 ] [Guo, Wen-hui]Peking Univ, Sch Phys, Yangtze Delta Inst Optoelect, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 5 ] [Lu, Jing]Peking Univ, Sch Phys, Yangtze Delta Inst Optoelect, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 6 ] [Wang, Xinqiang]Peking Univ, Sch Phys, Yangtze Delta Inst Optoelect, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 7 ] [Shi, Jun-jie]Peking Univ, Sch Phys, Yangtze Delta Inst Optoelect, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China
  • [ 8 ] [Zhu, Yao-hui]Beijing Technol & Business Univ, Phys Dept, Beijing 100048, Peoples R China
  • [ 9 ] [Du, Juan]Beijing Univ Technol, Fac Sci, Dept Phys & Optoelect Engn, Beijing 100124, Peoples R China
  • [ 10 ] [Zhong, Hong-xia]China Univ Geosci, Sch Math & Phys, Wuhan 430074, Peoples R China

Reprint Author's Address:

  • [Shi, Jun-jie]Peking Univ, Sch Phys, Yangtze Delta Inst Optoelect, State Key Lab Artificial Microstruct & Mesoscop Ph, Beijing 100871, Peoples R China;;[Zhu, Yao-hui]Beijing Technol & Business Univ, Phys Dept, Beijing 100048, Peoples R China;;[Du, Juan]Beijing Univ Technol, Fac Sci, Dept Phys & Optoelect Engn, Beijing 100124, Peoples R China;;

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Source :

ADVANCED FUNCTIONAL MATERIALS

ISSN: 1616-301X

Year: 2023

Issue: 11

Volume: 34

1 9 . 0 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 10

SCOPUS Cited Count: 9

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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