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Author:

He, Yong (He, Yong.) | Du, Juan (Du, Juan.) | Liu, Shi-ming (Liu, Shi-ming.) | Tian, Chong (Tian, Chong.) | Zhang, Min (Zhang, Min.) | Zhu, Yao-hui (Zhu, Yao-hui.) | Zhong, Hong-xia (Zhong, Hong-xia.) | Wang, Xinqiang (Wang, Xinqiang.) | Shi, Jun-jie (Shi, Jun-jie.)

Indexed by:

EI Scopus SCIE

Abstract:

In the search for high-temperature superconductivity in hydrides, a plethora of multi-hydrogen superconductors have been theoretically predicted, and some have been synthesized experimentally under ultrahigh pressures of several hundred GPa. However, the impracticality of these high-pressure methods has been a persistent issue. In response, we propose a new approach to achieve high-temperature superconductivity under ambient pressure by implanting hydrogen into lead to create a stable few-hydrogen binary perovskite, Pb4H. This approach diverges from the popular design methodology of multi-hydrogen covalent high critical temperature (Tc ) superconductors under ultrahigh pressure. By solving the anisotropic Migdal-Eliashberg equations, we demonstrate that perovskite Pb4H presents a phonon-mediated superconductivity exceeding 46 K with inclusion of spin-orbit coupling, which is six times higher than that of bulk Pb (7.22 K) and comparable to that of MgB2, the highest Tc achieved experimentally at ambient pressure under the Bardeen, Cooper, and Schrieffer framework. The high Tc can be attributed to the strong electron-phonon coupling strength of 2.45, which arises from hydrogen implantation in lead that induces several high-frequency optical phonon modes with a relatively large phonon linewidth resulting from H atom vibration. The metallic-bonding in perovskite Pb4H not only improves the structural stability but also guarantees better ductility than the widely investigated multi-hydrogen, iron-based and cuprate superconductors. These results suggest that there is potential for the exploration of new high-temperature superconductors under ambient pressure and may reignite interest in their experimental synthesis in the near future.

Keyword:

Migdal-Eliashberg theory first-principles calculations superconductivity electron-phonon coupling hydride

Author Community:

  • [ 1 ] [He, Yong]Peking Univ Yangtze Delta Inst Optoelect, State Key Lab Artificial Microstruct & Mesoscop Ph, Sch Phys, Yangtze Delta Inst Optoelect, Beijing 100871, Peoples R China
  • [ 2 ] [Liu, Shi-ming]Peking Univ Yangtze Delta Inst Optoelect, State Key Lab Artificial Microstruct & Mesoscop Ph, Sch Phys, Yangtze Delta Inst Optoelect, Beijing 100871, Peoples R China
  • [ 3 ] [Tian, Chong]Peking Univ Yangtze Delta Inst Optoelect, State Key Lab Artificial Microstruct & Mesoscop Ph, Sch Phys, Yangtze Delta Inst Optoelect, Beijing 100871, Peoples R China
  • [ 4 ] [Wang, Xinqiang]Peking Univ Yangtze Delta Inst Optoelect, State Key Lab Artificial Microstruct & Mesoscop Ph, Sch Phys, Yangtze Delta Inst Optoelect, Beijing 100871, Peoples R China
  • [ 5 ] [Shi, Jun-jie]Peking Univ Yangtze Delta Inst Optoelect, State Key Lab Artificial Microstruct & Mesoscop Ph, Sch Phys, Yangtze Delta Inst Optoelect, Beijing 100871, Peoples R China
  • [ 6 ] [Du, Juan]Beijing Univ Technol, Sch Phys & Optoelect Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Zhang, Min]Inner Mongolia Normal Univ, Coll Phys & Elect Informat, Inner Mongolia Key Lab Phys & Chem Funct Mat, Hohhot 010022, Peoples R China
  • [ 8 ] [Zhu, Yao-hui]Beijing Technol & Business Univ, Phys Dept, Beijing 100048, Peoples R China
  • [ 9 ] [Zhong, Hong-xia]China Univ Geosci, Sch Math & Phys, Wuhan 430074, Peoples R China

Reprint Author's Address:

  • [Shi, Jun-jie]Peking Univ Yangtze Delta Inst Optoelect, State Key Lab Artificial Microstruct & Mesoscop Ph, Sch Phys, Yangtze Delta Inst Optoelect, Beijing 100871, Peoples R China;;[Du, Juan]Beijing Univ Technol, Sch Phys & Optoelect Engn, Beijing 100124, Peoples R China

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Source :

JOURNAL OF PHYSICS-CONDENSED MATTER

ISSN: 0953-8984

Year: 2024

Issue: 20

Volume: 36

2 . 7 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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