Copious Dislocations Defect in Amorphous/Crystalline/Amorphous Sandwiched Structure P-NiMoO4 Electrocatalyst toward Enhanced Hydrogen Evolution Reaction - Details

Author：

Indexed by：

EI Scopus SCIE

Abstract：

The　design　and　synthesis　of　efficient,　inexpensive,　and　long-term　stable　heterostructured　electrocatalysts　with　high-density　dislocations　for　hydrogen　evolution　reaction　in　alkaline　media　and　seawater　are　still　a　great　challenge.　An　amorphous/crystalline/amorphous　sandwiched　structure　with　abundant　dislocations　were　synthesized　through　thermal　phosphidation　strategies.　The　dislocations　play　an　important　role　in　the　hydrogen　evolution　reactions.　Copious　dislocation　defects,　combined　with　cracks,　and　the　synergistic　interfacial　effect　between　crystalline　phase　and　amorphous　phase　regulate　the　electronic　structure　of　electrocatalyst,　provide　more　active　sites,　and　thus　endow　the　electrocatalysts　with　excellent　catalytic　activity　under　alkaline　water　and　seawater.　The　overpotentials　of　P-NiMoO4　at　10　mA/cm2　in　1　M　KOH　aqueous　solution　and　seawater　are　45　and　75　mV,　respectively.　Additionally,　the　P-NiMoO4　electrocatalyst　exhibits　long-term　stability　over　100　h.　This　study　provides　a　simple　approach　for　synthesizing　amorphous/crystalline/amorphous　sandwiched　non-noble-metal　electrocatalysts　with　abundant　dislocations　for　hydrogen　evolution　reaction.　©　2024　American　Chemical　Society.

Keyword：

hydrogen evolution reaction dislocation transition metal oxide sandwiched structure electrocatalysts

Author Community：

[ 1 ] [Zhang K.]School of Materials Science & Engineering, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 2 ] [Zhang K.]Materials Institute of Atomic and Molecular Science, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 3 ] [Su Q.]Materials Institute of Atomic and Molecular Science, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 4 ] [Shi W.]School of Materials Science & Engineering, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 5 ] [Shi W.]Materials Institute of Atomic and Molecular Science, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 6 ] [Lv Y.]School of Materials Science & Engineering, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 7 ] [Lv Y.]Materials Institute of Atomic and Molecular Science, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 8 ] [Zhu R.]School of Materials Science & Engineering, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 9 ] [Zhu R.]Materials Institute of Atomic and Molecular Science, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 10 ] [Wang Z.]Materials Institute of Atomic and Molecular Science, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 11 ] [Wang Z.]Beijing University of Technology, Chaoyang District, Beijing, 100124, China
[ 12 ] [Zhao W.]Materials Institute of Atomic and Molecular Science, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 13 ] [Zhang M.]Materials Institute of Atomic and Molecular Science, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 14 ] [Ding S.]Materials Institute of Atomic and Molecular Science, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 15 ] [Ma S.]Materials Institute of Atomic and Molecular Science, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 16 ] [Du G.]Materials Institute of Atomic and Molecular Science, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 17 ] [Xu B.]Materials Institute of Atomic and Molecular Science, Shaanxi University of Science and Technology, Xi’an, 710021, China
[ 18 ] [Xu B.]Key Laboratory of Interface Science and Engineering in Advanced Materials, Taiyuan University of Technology, Taiyuan, 030024, China
[ 19 ] [Xu B.]Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering, Taiyuan, 030032, China

Reprint Author's Address：

Email：

Show more details

Related Keywords：

Edge dislocation-induced strains break the limit of PtNi alloys in boosting Pt mass activity for efficient alkaline hydrogen evolution
2024，Nano Research
Recent advances of single-atom electrocatalysts for hydrogen evolution reaction
2021，JOURNAL OF PHYSICS-MATERIALS
Ultra-small carbon-supported FeRu alloy as a superior electrocatalyst for hydrogen evolution reaction; [具有优越电催化析氢性能的超小碳负载FeRu合金]
2023，Science China Materials
Topologically Close-Packed Frank-Kasper C15 Phase Intermetallic Ir Alloy Electrocatalysts Enables High-Performance Proton Exchange Membrane Water Electrolyzer
2024，ADVANCED MATERIALS

Source ：

ACS Nano

ISSN： 1936-0851

Year： 2024

Issue： 4

Volume： 18

Page： 3791-3800

1 7 . 1 0 0

JCR@2022

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count： 28

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS

Type
Departments

All Years Choose Year From to