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Author：

Liu, L. (Liu, L..) | Wang, J. (Wang, J..) | Feng, X. (Feng, X..) | Xu, K. (Xu, K..) | Liu, W. (Liu, W..) | Peng, X. (Peng, X..) | Du, H. (Du, H..) | Tan, J. (Tan, J..)

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Scopus SCIE

Abstract：

A　visible-light-enabled,　photocatalyst-free　hydroacylation　reaction　of　azodicarboxylic　acid　derivatives　was　described.　This　radical　conjugate　addition　(RCA)　protocol　relied　on　the　dual　role　of　4-acyl-1,4-dihydropyridine　(acyl-DHP)　reagents　that　besides　being　as　radical　reservoirs,　they　also　enabled　the　conversion　of　radical　adducts　to　anion　intermediates　via　reduction.　Under　“catalyst-oxidant-additive　free”　conditions,　a　wide　range　of　structurally　different　acyl　hydrazide　products　were　readily　obtained　in　56%—99%　yields.　The　utility　of　this　transformation　was　further　demonstrated　by　the　scale-up　synthesis　and　downstream　derivatization.　©　2024　SIOC,　CAS,　Shanghai,　&　WILEY-VCH　GmbH.

Keyword：

4-Acyl-1,4-dihydropyridine Azo compounds Acylation Photochemistry Radicals

Author Community：

  • [ 1 ] [Liu L.]Department of Organic Chemistry, College of Chemistry, Beijing University of Chemical Technology, Beijing, 100029, China
  • [ 2 ] [Liu L.]Sinopec Beijing Research Institute of Chemical Industry, Beijing, 100013, China
  • [ 3 ] [Wang J.]Department of Organic Chemistry, College of Chemistry, Beijing University of Chemical Technology, Beijing, 100029, China
  • [ 4 ] [Feng X.]Department of Organic Chemistry, College of Chemistry, Beijing University of Chemical Technology, Beijing, 100029, China
  • [ 5 ] [Xu K.]Faculty of Environment and Life, Beijing University of Technology, Beijing, 100124, China
  • [ 6 ] [Liu W.]Department of Organic Chemistry, College of Chemistry, Beijing University of Chemical Technology, Beijing, 100029, China
  • [ 7 ] [Peng X.]Department of Organic Chemistry, College of Chemistry, Beijing University of Chemical Technology, Beijing, 100029, China
  • [ 8 ] [Du H.]Department of Organic Chemistry, College of Chemistry, Beijing University of Chemical Technology, Beijing, 100029, China
  • [ 9 ] [Tan J.]Department of Organic Chemistry, College of Chemistry, Beijing University of Chemical Technology, Beijing, 100029, China

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Source ：

Chinese Journal of Chemistry

ISSN： 1001-604X

Year： 2024

Issue： 11

Volume： 42

Page： 1230-1236

5 . 4 0 0

JCR@2022

Cited Count：

WoS CC Cited Count： 0

SCOPUS Cited Count： 6

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 5

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