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Abstract:
The development of efficient all perovskite tandem solar cells has faced challenges related to current matching and optical losses. In this work, a design of a non-coplanar three-terminal (3T) all perovskite tandem solar cell is presented, which consists of a p-i-n inverted NiOX-based CsPbI2Br perovskite top cell, and a FA(0.6)MA(0.4)Sn(0.5)Pb(0.5)I(3) perovskite bottom cell with back-contact (BC) device structure. It effectively mitigated the optical losses introduced in non-absorbing layers and resulted in a 2.9% absolute efficiency improvement compared to that of planar sandwich-type 3T tandems. Both optical and electrical characteristics of the multi-terminal tandem cells are investigated. Then, it is focused on understanding the impact of top cell thickness on overall non-coplanar BC 3T-tandem performance, considering low-energy photon optical reflection and carrier transport distance. Following optimizations of energy level and device structure, an efficiency of 32.16% is achieved, with non-coplanar BC 3T device architecture: top cell consisting of hole extraction layer (ITO/NiOx), CsPbI2Br absorber layer, and electron extraction layer (ZnO/FA(0.6)MA(0.4)Sn(0.5)Pb(0.5)I(3)/SnO2/Ag); and bottom cell (Ni/NiOx/FA(0.6)MA(0.4)Sn(0.5)Pb(0.5)I(3)/SnO2/Ag); bottom perovskite layer has two functions, one is electron transport layer for top cell, and the other is low-energy photon absorption layer in bottom cell. It provides insight and a promising pathway for manufacturing high-efficient all perovskite tandem solar cells.
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ADVANCED FUNCTIONAL MATERIALS
ISSN: 1616-301X
Year: 2024
Issue: 29
Volume: 34
1 9 . 0 0 0
JCR@2022
Cited Count:
SCOPUS Cited Count: 5
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 8
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