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Author:

Yang, Xiqi (Yang, Xiqi.) | Zhou, Wencai (Zhou, Wencai.) | He, Yongcai (He, Yongcai.) | Sun, Zhaoqing (Sun, Zhaoqing.) | Zeng, Qinghua (Zeng, Qinghua.) | Yan, Hui (Yan, Hui.) | Zheng, Zilong (Zheng, Zilong.) | Chen, Xiaoqing (Chen, Xiaoqing.) | Tang, Zeguo (Tang, Zeguo.) | Zhang, Jinyan (Zhang, Jinyan.)

Indexed by:

EI Scopus SCIE

Abstract:

The development of efficient all perovskite tandem solar cells has faced challenges related to current matching and optical losses. In this work, a design of a non-coplanar three-terminal (3T) all perovskite tandem solar cell is presented, which consists of a p-i-n inverted NiOX-based CsPbI2Br perovskite top cell, and a FA(0.6)MA(0.4)Sn(0.5)Pb(0.5)I(3) perovskite bottom cell with back-contact (BC) device structure. It effectively mitigated the optical losses introduced in non-absorbing layers and resulted in a 2.9% absolute efficiency improvement compared to that of planar sandwich-type 3T tandems. Both optical and electrical characteristics of the multi-terminal tandem cells are investigated. Then, it is focused on understanding the impact of top cell thickness on overall non-coplanar BC 3T-tandem performance, considering low-energy photon optical reflection and carrier transport distance. Following optimizations of energy level and device structure, an efficiency of 32.16% is achieved, with non-coplanar BC 3T device architecture: top cell consisting of hole extraction layer (ITO/NiOx), CsPbI2Br absorber layer, and electron extraction layer (ZnO/FA(0.6)MA(0.4)Sn(0.5)Pb(0.5)I(3)/SnO2/Ag); and bottom cell (Ni/NiOx/FA(0.6)MA(0.4)Sn(0.5)Pb(0.5)I(3)/SnO2/Ag); bottom perovskite layer has two functions, one is electron transport layer for top cell, and the other is low-energy photon absorption layer in bottom cell. It provides insight and a promising pathway for manufacturing high-efficient all perovskite tandem solar cells.

Keyword:

tandem solar cells perovskite NiOx-based back contact three terminal

Author Community:

  • [ 1 ] [Yang, Xiqi]Shenzhen Technol Univ, Coll New Mat & New Energies, Lantian Rd 3002, Shenzhen 518118, Peoples R China
  • [ 2 ] [Tang, Zeguo]Shenzhen Technol Univ, Coll New Mat & New Energies, Lantian Rd 3002, Shenzhen 518118, Peoples R China
  • [ 3 ] [Yang, Xiqi]Beijing Univ Technol, Fac Mat & Mfg, Fac Informat Technol, Beijing 100124, Peoples R China
  • [ 4 ] [Zhou, Wencai]Beijing Univ Technol, Fac Mat & Mfg, Fac Informat Technol, Beijing 100124, Peoples R China
  • [ 5 ] [He, Yongcai]Beijing Univ Technol, Fac Mat & Mfg, Fac Informat Technol, Beijing 100124, Peoples R China
  • [ 6 ] [Sun, Zhaoqing]Beijing Univ Technol, Fac Mat & Mfg, Fac Informat Technol, Beijing 100124, Peoples R China
  • [ 7 ] [Yan, Hui]Beijing Univ Technol, Fac Mat & Mfg, Fac Informat Technol, Beijing 100124, Peoples R China
  • [ 8 ] [Zheng, Zilong]Beijing Univ Technol, Fac Mat & Mfg, Fac Informat Technol, Beijing 100124, Peoples R China
  • [ 9 ] [Chen, Xiaoqing]Beijing Univ Technol, Fac Mat & Mfg, Fac Informat Technol, Beijing 100124, Peoples R China
  • [ 10 ] [Zeng, Qinghua]Gold Stone Fujian Energy Co Ltd, Quanzhou 362005, Peoples R China
  • [ 11 ] [Zhang, Jinyan]Gold Stone Fujian Energy Co Ltd, Quanzhou 362005, Peoples R China

Reprint Author's Address:

  • [Tang, Zeguo]Shenzhen Technol Univ, Coll New Mat & New Energies, Lantian Rd 3002, Shenzhen 518118, Peoples R China;;[Zheng, Zilong]Beijing Univ Technol, Fac Mat & Mfg, Fac Informat Technol, Beijing 100124, Peoples R China;;[Chen, Xiaoqing]Beijing Univ Technol, Fac Mat & Mfg, Fac Informat Technol, Beijing 100124, Peoples R China

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Source :

ADVANCED FUNCTIONAL MATERIALS

ISSN: 1616-301X

Year: 2024

Issue: 29

Volume: 34

1 9 . 0 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

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