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Abstract:
In order to analyze the compatibility between the molten salt of the third generation solar thermal power generation technology and the materials of cryogenic tank,this article takes a mixed molten salt with low melting point(142 ℃)and high decomposition temperature(>700 ℃)as the corrosion environment,and studies the corrosion behavior of carbon steel(A515Gr70)and two low alloy steels(Q345R,15CrMoR)in the mixed molten salt at 450 ℃ through static corrosion experiments. The weight-loss method is adopted to measure the corrosion rates of different metals. The microstructure,phase composition and micro-area composition of the metal corrosion surface are analyzed by SEM,XRD and EDS. The results show that carbon steel does not contain corrosion resistant elements Cr,Ni and Mo,and the corrosion rate is the highest.The oxide layer on the surface of 15CrMoR is mainly composed of porous Fe2O3,which cannot prevent molten salt from immersing into the metal matrix,resulting in increased oxidation and poor corrosion resistance.The oxide layer on the surface of Q345R is composed of FeCr2O4,NiO and TiO2 with good compactness,which has a protective effect on the metal matrix and has the best corrosion resistance. © 2024 Science Press. All rights reserved.
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Source :
Acta Energiae Solaris Sinica
ISSN: 0254-0096
Year: 2024
Issue: 4
Volume: 45
Page: 540-545
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 4
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