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To improve catalytic activity and sulfur dioxide and water resistance of the 0.25Pt/TiO2 catalyst and explore the simple catalyst preparation method suitable for industrial production, we developed a 0.25Pt-CoOx/TiO2 catalyst in the present work. The 0.25Pt-CoOx/TiO2 catalyst was prepared via the impregnation-, precipitation-, and ball milling-combined method, and its catalytic CO oxidation performance as well as sulfur dioxide and water resistance was examined. It was shown that the 0.25Pt-CoOx/TiO2 catalyst exhibited a good catalytic activity and good resistance to sulfur dioxide and water. The T50, T90, and T100 (the temperatures for achieving CO conversions of 50, 90, and 100%) over the 0.25Pt-CoOx/TiO2 catalyst at a space velocity of 47,872 mL/(g h) were 95, 110, and 120 degrees C, which were 70, 57, and 50 degrees C lower than those over the 0.25Pt/TiO2 catalyst, respectively. Meanwhile, CO conversions over 0.25Pt-CoOx/TiO2 were maintained at above 99% within 12 h of reaction in the co-presence of SO2 and H2O. The doping of CoOx to 0.25Pt/TiO2 increased the surface Co3+ species concentration, redox ability, and acid site number of the 0.25Pt-CoOx/TiO2 catalyst, which favored the enhancements in catalytic activity and SO2- and H2O-resistant performance. In addition, it was also found that an appropriate amount of H2O introduction to the reaction system could promote the oxidation of CO and inhibit the negative effect of SO2 addition on CO oxidation over 0.25Pt-CoOx/TiO2, thus making this catalyst show good CO oxidation activity and good sulfur dioxide and water resistance. We are sure that the developed 0.25Pt-CoOx/ TiO2 catalyst has a great application potential in the removal of the flue gas emissions from the iron and steel industries.
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SURFACES AND INTERFACES
ISSN: 2468-0230
Year: 2024
Volume: 51
6 . 2 0 0
JCR@2022
Cited Count:
SCOPUS Cited Count: 2
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
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