• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
搜索

Author:

Cai, Jianyu (Cai, Jianyu.) | He, Junda (He, Junda.) | Yu, Zehui (Yu, Zehui.) | Li, Jian (Li, Jian.) | Fan, Xing (Fan, Xing.) | Liang, Wenjun (Liang, Wenjun.) | Dai, Hongxing (Dai, Hongxing.) (Scholars:戴洪兴)

Indexed by:

Scopus SCIE

Abstract:

To improve catalytic activity and sulfur dioxide and water resistance of the 0.25Pt/TiO2 catalyst and explore the simple catalyst preparation method suitable for industrial production, we developed a 0.25Pt-CoOx/TiO2 catalyst in the present work. The 0.25Pt-CoOx/TiO2 catalyst was prepared via the impregnation-, precipitation-, and ball milling-combined method, and its catalytic CO oxidation performance as well as sulfur dioxide and water resistance was examined. It was shown that the 0.25Pt-CoOx/TiO2 catalyst exhibited a good catalytic activity and good resistance to sulfur dioxide and water. The T50, T90, and T100 (the temperatures for achieving CO conversions of 50, 90, and 100%) over the 0.25Pt-CoOx/TiO2 catalyst at a space velocity of 47,872 mL/(g h) were 95, 110, and 120 degrees C, which were 70, 57, and 50 degrees C lower than those over the 0.25Pt/TiO2 catalyst, respectively. Meanwhile, CO conversions over 0.25Pt-CoOx/TiO2 were maintained at above 99% within 12 h of reaction in the co-presence of SO2 and H2O. The doping of CoOx to 0.25Pt/TiO2 increased the surface Co3+ species concentration, redox ability, and acid site number of the 0.25Pt-CoOx/TiO2 catalyst, which favored the enhancements in catalytic activity and SO2- and H2O-resistant performance. In addition, it was also found that an appropriate amount of H2O introduction to the reaction system could promote the oxidation of CO and inhibit the negative effect of SO2 addition on CO oxidation over 0.25Pt-CoOx/TiO2, thus making this catalyst show good CO oxidation activity and good sulfur dioxide and water resistance. We are sure that the developed 0.25Pt-CoOx/ TiO2 catalyst has a great application potential in the removal of the flue gas emissions from the iron and steel industries.

Keyword:

Titania -supported platinum catalyst Carbon monoxide oxidation Sulfur dioxide resistance Water resistance Cobalt oxide doping

Author Community:

  • [ 1 ] [Cai, Jianyu]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 2 ] [He, Junda]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 3 ] [Yu, Zehui]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 4 ] [Li, Jian]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 5 ] [Fan, Xing]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 6 ] [Liang, Wenjun]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 7 ] [Dai, Hongxing]Beijing Univ Technol, Coll Mat Sci & Engn, Dept Chem Engn & Technol,Key Lab Advanced Funct Ma, Beijing Key Lab Green Catalysis & Separat,Educ Min, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Fan, Xing]Beijing Univ Technol, Coll Environm Sci & Engn, Dept Environm Engn, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Coll Mat Sci & Engn, Dept Chem Engn & Technol,Key Lab Advanced Funct Ma, Beijing Key Lab Green Catalysis & Separat,Educ Min, Beijing 100124, Peoples R China;;

Show more details

Related Keywords:

Source :

SURFACES AND INTERFACES

ISSN: 2468-0230

Year: 2024

Volume: 51

6 . 2 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

Affiliated Colleges:

Online/Total:485/10713264
Address:BJUT Library(100 Pingleyuan,Chaoyang District,Beijing 100124, China Post Code:100124) Contact Us:010-67392185
Copyright:BJUT Library Technical Support:Beijing Aegean Software Co., Ltd.