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Author:

Zheng, Changlong (Zheng, Changlong.) | Pang, Dawei (Pang, Dawei.) | Jin, Baofang (Jin, Baofang.) | Wu, Xiaodong (Wu, Xiaodong.) | Liu, Shuang (Liu, Shuang.) | Ran, Rui (Ran, Rui.) | Weng, Duan (Weng, Duan.)

Indexed by:

EI Scopus SCIE

Abstract:

It has been generally accepted that active oxygen generation capability and wetting effect of catalyst have a significant influence on catalytic soot oxidation with O2. Thus, these two factors were investigated for low Tammann temperature Ru-based materials in soot oxidation reaction, with Pt/Al2O3 as a reference catalyst. The catalysts were characterized by O2 temperature-programmed desorption (O2-TPD), soot temperatureprogrammed reduction (soot-TPR) and environmental transmission electron microscope (ETEM), cycled H2 temperature-programmed reduction (cycled-TPR), cyclic thermogravimetric analysis (cyclic TG), in-situ X-ray Diffraction (in-situ XRD), et al. Based on the soot temperature-programmed oxidation (soot-TPO) and kinetic studies, Ru/Al2O3 demonstrates a much better catalytic activity than Pt/Al2O3. ETEM images indicates further RuO2 particles do not move during soot oxidation and hereby wetting effect does not play a critical role. The O2TPD and soot-TPR results indicate that Ru/Al2O3 exhibits superior oxygen dissociating ability and possesses more active oxygen species compared with Pt/Al2O3. The cycled-TPR and cyclic-TG findings further confirm the excellent regeneration ability of active oxygen species on Ru/Al2O3 which arises importantly from the release of lattice oxygen in RuO2 and refilling of oxygen vacancies with gaseous oxygen. Such superior oxygen activation and regeneration ability even reverse the contacting trend of the solid-solid-gas reaction. Surprisingly, high activity is achieved over this catalyst under loose contact conditions in comparison with the tight contact case, which depends on competition between O2 transfer and O2 activation.

Keyword:

Soot oxidation Active oxygen regeneration In-situ XRD ETEM

Author Community:

  • [ 1 ] [Zheng, Changlong]Tsinghua Univ, Minist Educ, Sch Mat Sci & Engn, Key Lab Adv Mat, Beijing 100084, Peoples R China
  • [ 2 ] [Jin, Baofang]Tsinghua Univ, Minist Educ, Sch Mat Sci & Engn, Key Lab Adv Mat, Beijing 100084, Peoples R China
  • [ 3 ] [Wu, Xiaodong]Tsinghua Univ, Minist Educ, Sch Mat Sci & Engn, Key Lab Adv Mat, Beijing 100084, Peoples R China
  • [ 4 ] [Weng, Duan]Tsinghua Univ, Minist Educ, Sch Mat Sci & Engn, Key Lab Adv Mat, Beijing 100084, Peoples R China
  • [ 5 ] [Pang, Dawei]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Wu, Xiaodong]Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
  • [ 7 ] [Ran, Rui]Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
  • [ 8 ] [Liu, Shuang]Ocean Univ China, Sch Mat Sci & Engn, Qingdao 266100, Peoples R China
  • [ 9 ] [Jin, Baofang]Northeast Petr Univ, Qinhuangdao Key Lab Dev & Pollut Prevent Marine Oi, Dept Petr & Chem Engn, Qinhuangdao 066004, Hebei, Peoples R China

Reprint Author's Address:

  • [Wu, Xiaodong]Tsinghua Univ, Minist Educ, Sch Mat Sci & Engn, Key Lab Adv Mat, Beijing 100084, Peoples R China

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Source :

SEPARATION AND PURIFICATION TECHNOLOGY

ISSN: 1383-5866

Year: 2025

Volume: 361

8 . 6 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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