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Author:

Zhang, F. P. (Zhang, F. P..) | Shi, J. L. (Shi, J. L..) | Zhang, J. W. (Zhang, J. W..) (Scholars:张建伟) | Yang, X. Y. (Yang, X. Y..) | Zhang, J. X. (Zhang, J. X..)

Indexed by:

Scopus SCIE

Abstract:

The polycrystalline Ca3Co4O9 oxide powders were synthesized by citrate acid sol-gel method, and the Ca3Co4O9 oxide ceramics with diverse grain alignments were prepared by sintering the pressed pellet bulks through controlling the procedures, respectively. The phase compositions, grain alignments, bulk microstructures, textures as well as the electrical transport properties were investigated by means of X-ray diffraction pattern XRD, scanning electron microscopy SEM, transmission electron microscopy TEM and electrical constant measurements apparatus. The results showed that the obtained Ca3Co4O9 ceramics with uniformly single phases and diverse grain alignments can be fabricated by modulating the preparing parameters; moreover, the grain alignment can be enhanced by applying the pressure of the sintering procedure. The Ca3Co4O9 ceramics with uniformly single phase and strongest grain alignment could be fabricated with formation pressure of 500 MPa and sintering pressure of 30 MPa. The sintering pressure is a key factor enhancing the grain alignment for this type of ceramics. The ceramic sample with highest grain alignment was found to have the highest electrical properties, which showed the maximum power factor value of 3.83 mu W cm(-1) K-2 at 700 degrees C.

Keyword:

Electrical transport properties Preparation Ca3Co4O9 ceramics Grain alignments

Author Community:

  • [ 1 ] [Zhang, F. P.]Henan Univ Urban Construct, Henan Prov Engn Lab Bldg Photovolta, Inst Phys, Pingdingshan 467036, Henan, Peoples R China
  • [ 2 ] [Zhang, J. X.]Henan Univ Urban Construct, Henan Prov Engn Lab Bldg Photovolta, Inst Phys, Pingdingshan 467036, Henan, Peoples R China
  • [ 3 ] [Zhang, F. P.]Beijing Univ Technol, Natl Key Lab Adv Funct Mat, Chinese Minist Educ, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Zhang, J. X.]Beijing Univ Technol, Natl Key Lab Adv Funct Mat, Chinese Minist Educ, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Shi, J. L.]Hefei Univ Technol, Anhui Prov Key Lab Adv Funct Mat & Devices, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 6 ] [Zhang, J. W.]Hefei Univ Technol, Anhui Prov Key Lab Adv Funct Mat & Devices, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 7 ] [Yang, X. Y.]Hefei Univ Technol, Anhui Prov Key Lab Adv Funct Mat & Devices, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
  • [ 8 ] [Zhang, J. X.]Hefei Univ Technol, Anhui Prov Key Lab Adv Funct Mat & Devices, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China

Reprint Author's Address:

  • [Zhang, F. P.]Henan Univ Urban Construct, Henan Prov Engn Lab Bldg Photovolta, Inst Phys, Pingdingshan 467036, Henan, Peoples R China

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Source :

RESULTS IN PHYSICS

ISSN: 2211-3797

Year: 2019

Volume: 12

Page: 321-326

5 . 3 0 0

JCR@2022

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 11

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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