The　low-dimensional　halide　perovskites　have　received　enormous　attention　due　to　their　unique　photovoltaic　and　optoelectronic　performances.　Periodic　spacers　are　used　to　inhibit　the　growth　of　3D　perovskite　and　fabricate　a　2D　counterpart　with　layered　structure,　mostly　based　on　organic/inorganic　cations.　Herein,　by　introducing　organic　anions　(e.g.,　pentanedioic　acid　(PDA)　and　hexanedioic　acid　(HDA)　simultaneously),　leaf-shaped　(Cs3Pb2Br5)(2)(PDA-HDA)　microplates　with　low-dimensional　structure　are　synthesized.　They　also　exhibit　significant　photoluminescence　(PL)　centered　at　540　nm　with　a　narrow　emission　peak.　The　synthesis　of　single　crystals　of　Pb(PDA)　and　Pb(HDA)　allows　to　further　clarify　the　crystal　structure　of　(Cs3Pb2Br5)(2)(PDA-HDA)　perovskite　and　its　structural　evolution　mechanism.　Moreover,　the　cooperative　introduction　of　dicarboxylic　acid　pairs　with　appropriate　lengths　is　thermodynamically　favored　for　the　low-dimensional　perovskite　crystallization.　The　temperature-dependent　PL　indicates　a　V-shaped　Stokes　shift　with　elevated　temperature　that　could　be　associated　with　the　localization　of　excitons　in　the　inorganic　layers　between　organic　dicarboxylic　acid　molecules.　This　work　demonstrates　low-dimensional　halide　perovskite　with　anionic　spacers,　which　also　opens　up　a　new　approach　to　the　growth　of　low-dimensional　organic-inorganic　hybrid　perovskite　crystals.