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Abstract:
Tungsten carbide (WC) scrap was used as a consumable anode to prepare tungsten powder in NaCl-KCl melt at 1023 K for the first time. The electrolysis process was investigated. Results showed that the tungsten component in WC anode was dissolved as W2+ into the NaCl-KCl melt. The cathode reaction was controlled by the diffusion of tungsten ions. The effect of electrolysis parameters, including the anode-cathode distance, cathode current density and different electrolysis ways (galvanostatic and potentiostatic electrolysis), on the purity and grain size of the cathode deposits was studied. It showed that a large anode-cathode distance was beneficial to the formation of pure tungsten powder at the cathode. With increasing the cathode current density, the tungsten grain size first decreased and then increased. When the cathode current density was 0.125 A cm(-2), tungsten powder with a diameter of smaller than 100 nm was obtained. Deposits prepared through galvanostatic and potentiostatic electrolysis was compared in the end. (C) 2015 Elsevier Ltd. All rights reserved.
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INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS
ISSN: 0263-4368
Year: 2016
Volume: 54
Page: 422-426
3 . 6 0 0
JCR@2022
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:305
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 21
SCOPUS Cited Count: 23
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
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