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Author:

Wei Yuechang (Wei Yuechang.) | Liu Jian (Liu Jian.) | Zhao Zhen (Zhao Zhen.) | Jiang Guiyuan (Jiang Guiyuan.) | Duan Aijun (Duan Aijun.) | He Hong (He Hong.) (Scholars:何洪) | Wang Xinping (Wang Xinping.)

Indexed by:

EI Scopus SCIE PKU CSCD

Abstract:

A series of Cel(1-x)Zr(x)O(2) (x = 0, 0.2, 0.4, 0.5) solid solutions were prepared by the micropore-diffused coprecipitation method with ammonia solution as precipitation agent. Co-0.2/Ce1-xZrxO2 catalysts were prepared by the ultrasound-assisted incipient-wetness impregnation method. The effect of Ce/Zr molar ratio on the catalyst activity for soot combustion was investigated. The Co-0.2/Ce1-xZrxO2 catalysts gave very high activity for soot combustion under loose contact conditions between soot and catalyst, and the catalytic activity of Co-0.2/Ce0.8Zr0.2O2 catalyst was the highest, whose T-10, T-50, T-90, and (SCO2)-C-m were 316 degrees C, 385 degrees C, 413 degrees C, and 99.9%, respectively. Compared with when there was no catalyst, T-10, T-50, and T-90 decreased by 136, 197, and 226 degrees C, respectively, and S(m)co(2) increased by 45.9%. This catalytic activity for soot combustion was as good as that of supported Pt catalysts, which was the best catalyst system so far reported for soot combustion under loose contact conditions. All the samples were characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, Fourier transform infrared spectroscopy, and UV-Vis diffuse reflectance spectroscopy. The results showed that nanometer Ce1-xZrxO2 solid solution supports can be prepared by the micropore-diffused coprecipitation method. The average particle size of Ce1-xZrxO2 solid solutions was about 10 nm. Doping Zr affected the dispersion of Co over Ce1-xZrxO2 solid solutions. The right Ce/Zr molar

Keyword:

cobalt oxide soot combustion micropore-diffused coprecipitation solid solution zirconium cerium

Author Community:

  • [ 1 ] [Wei Yuechang]China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
  • [ 2 ] [Liu Jian]China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
  • [ 3 ] [Zhao Zhen]China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
  • [ 4 ] [Jiang Guiyuan]China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
  • [ 5 ] [Duan Aijun]China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
  • [ 6 ] [He Hong]Beijing Univ Technol, Coll Environm & Energy Engn, Dept Chem & Chem Engn, Beijing 100022, Peoples R China
  • [ 7 ] [Wang Xinping]Dalian Univ Technol, Coll Chem Engn, State Key Lab Fine Chem, Dalian 116024, Liaoning, Peoples R China

Reprint Author's Address:

  • [Wei Yuechang]China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China

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Source :

CHINESE JOURNAL OF CATALYSIS

ISSN: 0253-9837

Year: 2010

Issue: 3

Volume: 31

Page: 283-288

1 6 . 5 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 22

SCOPUS Cited Count: 29

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

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