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Abstract:
A series of Cel(1-x)Zr(x)O(2) (x = 0, 0.2, 0.4, 0.5) solid solutions were prepared by the micropore-diffused coprecipitation method with ammonia solution as precipitation agent. Co-0.2/Ce1-xZrxO2 catalysts were prepared by the ultrasound-assisted incipient-wetness impregnation method. The effect of Ce/Zr molar ratio on the catalyst activity for soot combustion was investigated. The Co-0.2/Ce1-xZrxO2 catalysts gave very high activity for soot combustion under loose contact conditions between soot and catalyst, and the catalytic activity of Co-0.2/Ce0.8Zr0.2O2 catalyst was the highest, whose T-10, T-50, T-90, and (SCO2)-C-m were 316 degrees C, 385 degrees C, 413 degrees C, and 99.9%, respectively. Compared with when there was no catalyst, T-10, T-50, and T-90 decreased by 136, 197, and 226 degrees C, respectively, and S(m)co(2) increased by 45.9%. This catalytic activity for soot combustion was as good as that of supported Pt catalysts, which was the best catalyst system so far reported for soot combustion under loose contact conditions. All the samples were characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, Fourier transform infrared spectroscopy, and UV-Vis diffuse reflectance spectroscopy. The results showed that nanometer Ce1-xZrxO2 solid solution supports can be prepared by the micropore-diffused coprecipitation method. The average particle size of Ce1-xZrxO2 solid solutions was about 10 nm. Doping Zr affected the dispersion of Co over Ce1-xZrxO2 solid solutions. The right Ce/Zr molar
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CHINESE JOURNAL OF CATALYSIS
ISSN: 0253-9837
Year: 2010
Issue: 3
Volume: 31
Page: 283-288
1 6 . 5 0 0
JCR@2022
ESI Discipline: CHEMISTRY;
JCR Journal Grade:3
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 22
SCOPUS Cited Count: 29
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 6
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