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Abstract:
Quenching alkaline bismuth titanates from sintering temperatures results in increased lattice distortion and consequently higher depolarization temperature. This work investigates the influence of quenching on the ergodicity of relaxor Na1/2Bi1/2TiO3-BaTiO3-K0.5Na0.5NbO3. A distinct departure from ergodicity is evidenced from the increase in remanent polarization and the absence of frequency dispersion in the permittivity response of poled samples. Further, the samples exhibit enhanced negative strain upon application of electric field, indicating proclivity towards correlated polar nanoregions, corroborated by the enhanced tetragonal distortion. As a result, ergodic relaxor Na1/2Bi1/2TiO3-6BaTiO(3)-3K(0.5)Na(0.5)NbO(3) exhibits a depolarization temperature of 85 degrees C with a 60% increase in remanent polarization and approximately a threefold increase in remanent strain upon quenching. Quenching-induced changes in the local environment of Na+ and Bi3+ cations hinder the development of ergodicity promoted by the A-site disorder. These results provide new insight into tailoring ergodicity of relaxor ferroelectrics.
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JOURNAL OF THE AMERICAN CERAMIC SOCIETY
ISSN: 0002-7820
Year: 2021
Issue: 7
Volume: 104
Page: 3316-3324
3 . 9 0 0
JCR@2022
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:116
JCR Journal Grade:1
Cited Count:
WoS CC Cited Count: 18
SCOPUS Cited Count: 17
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3
Affiliated Colleges: