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Author:

Lei, Chao (Lei, Chao.) | Peng, Chen-Wei (Peng, Chen-Wei.) | Zhong, Jun (Zhong, Jun.) | Li, Hongyu (Li, Hongyu.) | Yang, Miao (Yang, Miao.) | Zheng, Kun (Zheng, Kun.) (Scholars:郑坤) | Qu, Xianlin (Qu, Xianlin.) | Wu, Lili (Wu, Lili.) | Yu, Cao (Yu, Cao.) | Li, Yuanmin (Li, Yuanmin.) | Xu, Xixiang (Xu, Xixiang.)

Indexed by:

EI Scopus SCIE

Abstract:

The current loss is mainly due to the reflection and the parasitic absorption in the indium tin oxide (ITO) and amorphous silicon (a-Si:H) in the front side of silicon heterojunction (SHJ) solar cells. In this paper, we implemented n-type hydrogenated microcrystalline silicon oxide (n-mu c-SiOx:H) as the front surface field (FSF) to improve the short-circuit current density (J(SC)) of SHJ solar cells. The advantage of employing n-mu c-SiOx:H layer is due to its low optical absorption coefficient and tunable refractive index. However, the introduction of carbon dioxide increases light transmission but reduces the crystallinity of n-mu c-SiOx:H layer. Meanwhile, inhibiting the incubation layer and increasing microcrystalline/amorphous mixture phase during the growth are critical to the solar cell performance. Therefore, we implemented a high phosphorus-doping seed layer to form a nucleation layer to improve the crystallinity of n-mu c-SiOx:H layer. In addition, the plasma enhanced chemical vapor deposition (PECVD) process parameters of each layer were optimized to obtain good optical and electrical properties of n-mu c-SiOx:H layer. Finally, a 242.5 cm(2) solar cell had been fabricated with conversion efficiency of 23.87%, open-circuit voltage (V-OC) of 739.8 mV, fill factor (FF) of 82.33% and J(SC) of 39.19 mA/cm(2), which was 0.31 mA/cm(2) higher than that of the conventional n type a-Si:H SHJ solar cells.

Keyword:

Microcrystalline silicon oxide Crystalline volume fraction Phosphorus treatment SHJ solar cells

Author Community:

  • [ 1 ] [Lei, Chao]Sichuan Univ, Coll Mat Sci & Engn, Inst Solar Energy Mat & Devices, 29 Wangjiang Rd, Chengdu 610064, Peoples R China
  • [ 2 ] [Li, Hongyu]Sichuan Univ, Coll Mat Sci & Engn, Inst Solar Energy Mat & Devices, 29 Wangjiang Rd, Chengdu 610064, Peoples R China
  • [ 3 ] [Wu, Lili]Sichuan Univ, Coll Mat Sci & Engn, Inst Solar Energy Mat & Devices, 29 Wangjiang Rd, Chengdu 610064, Peoples R China
  • [ 4 ] [Peng, Chen-Wei]Chengdu Zhufeng Yongming Technol Co Ltd, Chengdu 610200, Sichuan, Peoples R China
  • [ 5 ] [Zhong, Jun]Chengdu Zhufeng Yongming Technol Co Ltd, Chengdu 610200, Sichuan, Peoples R China
  • [ 6 ] [Yang, Miao]Chengdu Zhufeng Yongming Technol Co Ltd, Chengdu 610200, Sichuan, Peoples R China
  • [ 7 ] [Yu, Cao]Chengdu Zhufeng Yongming Technol Co Ltd, Chengdu 610200, Sichuan, Peoples R China
  • [ 8 ] [Li, Yuanmin]Chengdu Zhufeng Yongming Technol Co Ltd, Chengdu 610200, Sichuan, Peoples R China
  • [ 9 ] [Xu, Xixiang]Chengdu Zhufeng Yongming Technol Co Ltd, Chengdu 610200, Sichuan, Peoples R China
  • [ 10 ] [Zheng, Kun]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing Key Lab Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 11 ] [Qu, Xianlin]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing Key Lab Microstruct & Property Adv Mat, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Wu, Lili]Sichuan Univ, Coll Mat Sci & Engn, Inst Solar Energy Mat & Devices, 29 Wangjiang Rd, Chengdu 610064, Peoples R China;;[Yu, Cao]Chengdu Zhufeng Yongming Technol Co Ltd, Chengdu 610200, Sichuan, Peoples R China

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Source :

SOLAR ENERGY MATERIALS AND SOLAR CELLS

ISSN: 0927-0248

Year: 2020

Volume: 209

6 . 9 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:169

Cited Count:

WoS CC Cited Count: 24

SCOPUS Cited Count: 25

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 9

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