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Author:

Jin, Xiaodong (Jin, Xiaodong.) | Cui, Suping (Cui, Suping.) (Scholars:崔素萍) | Sun, Shibing (Sun, Shibing.) (Scholars:孙诗兵) | Gu, Xiaoyu (Gu, Xiaoyu.) | Li, Hongfei (Li, Hongfei.) | Sun, Jun (Sun, Jun.) | Zhang, Sheng (Zhang, Sheng.) | Bourbigot, Serge (Bourbigot, Serge.)

Indexed by:

SCIE

Abstract:

Owing to the biological compatibility and mechanical properties of polylactic acid (PLA), it presents an extensive application area (such as packaging, film, and fiber). However, the molten dripping phenomenon during combustion is still a drawback in the application of PLA. In this research, an intumescent flame retardant (A-A) was prepared based on the ionic exchange between p-aminobenzenesulfonic acid and ammonium polyphosphate. After that, A-A was molten compounded with PLA to improve its flame retardancy. It was suggested that the presence of 15% A-A could increase the limiting oxygen index value from 20.0% of neat PLA to 30.5%, enhance the UL results from none to V-0 and restrict the heat release during cone calorimeter test. Most importantly, the dripping behavior of PLA/15A-A composites while burning had been greatly minimized. On the basis of the mechanism analysis, it was suggested that A-A modified the initial degradation routine of PLA matrix, resulting to the rapid construction of protective barrier, thus endowing the antidripping property to the PLA/15A-A composites.

Keyword:

ionic exchange intumescent antidripping flame retardant polylactic acid

Author Community:

  • [ 1 ] [Jin, Xiaodong]Beijing Univ Technol, Collage Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Cui, Suping]Beijing Univ Technol, Collage Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Sun, Shibing]Beijing Univ Technol, Collage Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Jin, Xiaodong]Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
  • [ 5 ] [Gu, Xiaoyu]Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
  • [ 6 ] [Li, Hongfei]Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
  • [ 7 ] [Sun, Jun]Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
  • [ 8 ] [Zhang, Sheng]Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
  • [ 9 ] [Bourbigot, Serge]ENSCL ISP UMET, F-59652 Villeneuve Dascq, France

Reprint Author's Address:

  • 崔素萍

    [Cui, Suping]Beijing Univ Technol, Collage Mat Sci & Engn, Beijing 100124, Peoples R China;;[Zhang, Sheng]Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China

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Source :

ACS APPLIED POLYMER MATERIALS

ISSN: 2637-6105

Year: 2019

Issue: 4

Volume: 1

Page: 755-764

5 . 0 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 61

SCOPUS Cited Count: 59

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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