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Author:

Cao, Tianci (Cao, Tianci.) | Cheng, Xiaopeng (Cheng, Xiaopeng.) | Wu, Rui (Wu, Rui.) | Wang, Mingming (Wang, Mingming.) | Niu, Jiajia (Niu, Jiajia.) | Liu, Huan (Liu, Huan.) | Liu, Xianqiang (Liu, Xianqiang.) | Lu, Junxia (Lu, Junxia.) | Zhang, Yuefei (Zhang, Yuefei.) (Scholars:张跃飞)

Indexed by:

EI Scopus SCIE

Abstract:

Li metal is the prospective candidate of next generation anode materials. However, the growth of dendritic Li during electrochemical cycling has severely hindered the practical application of rechargeable Li-metal batteries. Herein, "seaweed" graphene paper (SGP) is designed for 3D matrix of Li metal anode to address the growth of dendrites. SGP has abundantly exposed edges of graphene sheets and realizes ultrahigh density nucleation. Compared with nonuniform lithium deposition on parallelly stacked GP which has been observed by in-situ scanning electron microscopy, electrochemical deposition behavior of Li in SGP manifests as uniformly distributed granular lithium. Significant decrease of nucleation barrier can be observed during the dendrite-free deposition. With the elimination of dendritic Li growth and excellent stability of SGP host, the lithium anode based on SGP can run over 2500 cycles without short circuit and exhibits low voltage hysteresis. When matched with cathode LiCoO2, the full battery also presents stable cycling. There is no trace of lithium dendrite even after 1200 cycles which proves continuously regulating effect on lithium dendrites by SGP host. This work further develops potential application of graphene materials in the Li anode with high reversibility for stable cycling Li metal batteries. (C) 2021 Elsevier Ltd. All rights reserved.

Keyword:

Li metal anodes Nucleation barrier Ultrahigh nucleation density Long dendrite-free cycling Graphene paper

Author Community:

  • [ 1 ] [Cao, Tianci]Beijing Univ Technol, Fac Mat & Mfg, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 2 ] [Cheng, Xiaopeng]Beijing Univ Technol, Fac Mat & Mfg, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 3 ] [Wu, Rui]Beijing Univ Technol, Fac Mat & Mfg, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 4 ] [Wang, Mingming]Beijing Univ Technol, Fac Mat & Mfg, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 5 ] [Niu, Jiajia]Beijing Univ Technol, Fac Mat & Mfg, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 6 ] [Liu, Huan]Beijing Univ Technol, Fac Mat & Mfg, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 7 ] [Liu, Xianqiang]Beijing Univ Technol, Fac Mat & Mfg, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 8 ] [Zhang, Yuefei]Beijing Univ Technol, Fac Mat & Mfg, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 9 ] [Lu, Junxia]Beijing Univ Technol, Fac Mat & Mfg, Inst Laser Engn, Beijing 100124, Peoples R China

Reprint Author's Address:

  • 张跃飞

    [Liu, Xianqiang]Beijing Univ Technol, Fac Mat & Mfg, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China;;[Zhang, Yuefei]Beijing Univ Technol, Fac Mat & Mfg, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China;;[Lu, Junxia]Beijing Univ Technol, Fac Mat & Mfg, Inst Laser Engn, Beijing 100124, Peoples R China

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Source :

CARBON

ISSN: 0008-6223

Year: 2021

Volume: 183

Page: 641-651

1 0 . 9 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:96

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

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