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Author:

Xu, GuoLiang (Xu, GuoLiang.) | Liu, DanMin (Liu, DanMin.) | Li, JingZhen (Li, JingZhen.) | Li, JingJie (Li, JingJie.) | Ye, ShuaiShuai (Ye, ShuaiShuai.)

Indexed by:

EI Scopus SCIE

Abstract:

A self-driven photosensor with signal-reversal response has the potential to work as a photodetector in complex environments with multiple signals owing to better signal recognition and enhanced signal-processing efficiency. Herein, a metal-semiconductor-metal photodetector based on ambipolar WSe2 with two electrodes comprising two-dimensional (2D) van der Waals (vdWs) metal Fe3GeTe2 and semimetal graphene was proposed to form an asymmetrical metal-contacted architecture with different Schottky barrier heights. The regulating gate field-induced Fermi level shift in WSe2 can be used to manipulate the WSe2 channel's carrier type, resulting in a polarity-reversible photodetector without a bias voltage. Furthermore, the photovoltaic effect can be observed from wavelengths of 450 nm (visible) to 850 nm (infrared) without external voltage. The large open voltage is -0.177 V and short-circuit current is 17 nA under a 650-nm excitation wavelength. The reported WSe2-based photodetector exhibits excellent properties under zero bias, including a large photo-to-dark current ratio greater than 10(6) with dark current less than 1 fA, photovoltaic performance with an external quantum efficiency of 27.14%, an excellent detectivity of 3.4x10(10) Jones, and a high responsivity of 116.38 mA/W. Rapid electron transfer occurs at the interface between WSe2 and vdWs electrodes, resulting in a 370-mu s response speed owing to the clean and nondestructive interfaces between vdWs metals and WSe2. This study demonstrates the wide application prospect of the vdWs metal Fe3GeTe2 as an electrode forming a Schottky junction for realizing a photodetector without an external voltage and accelerates the development of 2D photosensors with various working modes.

Keyword:

WSe2 van der Waals electrodes photodetector polarity-reversible zero-biased

Author Community:

  • [ 1 ] [Xu, GuoLiang]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [Liu, DanMin]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Li, JingJie]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Ye, ShuaiShuai]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 5 ] [Li, JingZhen]Beijing Univ Technol, Coll Microelect, Fac Informat Technol, Key Lab Optoelect Technol, Beijing 100124, Peoples R China

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Source :

SCIENCE CHINA-TECHNOLOGICAL SCIENCES

ISSN: 1674-7321

Year: 2022

Issue: 6

Volume: 65

Page: 1263-1272

4 . 6

JCR@2022

4 . 6 0 0

JCR@2022

ESI Discipline: ENGINEERING;

ESI HC Threshold:49

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count: 7

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

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