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Author:

Sun, Hao (Sun, Hao.) | Wang, Naixin (Wang, Naixin.) | Li, Xiaoting (Li, Xiaoting.) | An, Quan-Fu (An, Quan-Fu.) (Scholars:安全福)

Indexed by:

EI Scopus SCIE

Abstract:

In this study, metal-organic framework (MOF) layer on the surface of tubular ceramic substrate was prepared as the precursor template to construct ZIF-67-derived CoSx composite membrane through in-situ sulfurization strategy. During the sulfurization process, ZIF-67 as a template was reacted with sulfur ions to form CoSx. Due to the structure change of the ZIF-67 crystal, the aperture of the CoSx was enlarged with the thickness of the separation layer decreased. Moreover, the reorganization of the separation layer caused by the in-situ sulfurization eliminated the non-selective defects. Therefore, a CoSx composite membrane can be obtained with high separation performance and good stability for dye/salt separation. The effects of sulfurization and operation conditions on membrane performance were studied. The CoSx composite membrane had outstanding permeance (751.6 LMH/MPa) and excellent rejection (> 99.5%) for dye molecules, while the rejection for salt was below 18.7%. The separation performance of the CoSx composite membrane can be maintained over 100 h, which exhibited great potential in dye desalination.

Keyword:

In situ sulfurization Nanofiltration Dyes/salt separation MOF derivatives High permeance

Author Community:

  • [ 1 ] [Sun, Hao]Beijing Univ Technol, Dept Environm & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 2 ] [Wang, Naixin]Beijing Univ Technol, Dept Environm & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 3 ] [Li, Xiaoting]Beijing Univ Technol, Dept Environm & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China
  • [ 4 ] [An, Quan-Fu]Beijing Univ Technol, Dept Environm & Chem Engn, Beijing Key Lab Green Catalysis & Separat, Beijing 100124, Peoples R China

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Source :

JOURNAL OF MEMBRANE SCIENCE

ISSN: 0376-7388

Year: 2022

Volume: 645

9 . 5

JCR@2022

9 . 5 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:53

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 30

SCOPUS Cited Count: 31

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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