Prochloraz　(Pro)　controlled-release　nanoparticles　(NPs)　based　on　bimodal　mesoporous　silica　(BMMs)　with　redox　and　pH　dual　responses　were　successfully　prepared　in　this　study.　BMMs　was　modified　by　a　silane　coupling　agent　containing　a　disulfide　bond,　and　beta-cyclodextrin　(beta-CD)　was　grafted　on　the　surface　of　the　NPs　through　host-guest　interaction.　Pro　was　encapsulated　into　the　pores　of　nanoparticles　by　physical　adsorption.　NPs　had　a　spherical　structure,　and　their　average　diameter　was　546.4　+/-　3.0　nm　as　measured　by　dynamic　light　scattering.　The　loading　rate　of　Pro　was　28.3%,　and　it　achieved　excellent　pH/redox　dual-responsive　release　performance　under　acidic　conditions.　Foliage　adhesion　tests　on　tomato　leaves　showed　that　the　NPs　had　good　adhesion　properties　compared　to　the　commercial　formulation.　Owing　to　the　protection　of　the　nanocarrier,　NPs　became　more　stable　under　ultraviolet　light　and　high　temperature,　which　improves　the　efficient　utilization　of　Pro.　Biological　activity　tests　showed　that　the　NPs　exhibited　effective　antifungal　activity,　and　the　benign　biosafety　of　the　nanocarrier　was　also　observed　through　toxicology　tests　on　cell　viability　and　the　growth　of　Escherichia　coli　(E.　coli).　This　work　provides　a　promising　approach　to　improving　the　efficient　utilization　of　pesticides　and　reducing　environmental　pollution.