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Author:

Hu, Jingcong (Hu, Jingcong.) | Bi, Chenghao (Bi, Chenghao.) | Zhang, Xuetao (Zhang, Xuetao.) | Lu, Yue (Lu, Yue.) (Scholars:卢岳) | Zhou, Wencai (Zhou, Wencai.) | Zheng, Zilong (Zheng, Zilong.) | Tang, Ying (Tang, Ying.) | Lu, Feng (Lu, Feng.) | Yao, Zhiwei (Yao, Zhiwei.) | Tian, Bohai (Tian, Bohai.) | Wang, Xiaoyong (Wang, Xiaoyong.) | Selvakumar, Karuppaiah (Selvakumar, Karuppaiah.) | Tian, Jianjun (Tian, Jianjun.) | Sui, Manling (Sui, Manling.)

Indexed by:

EI Scopus SCIE

Abstract:

With the rapid development of metal halide perovskite, reducing its dimensionality into two-dimensional (2D) or one-dimensional (1D) nanostructures has been reported to be a good alternative for expanding the spectral absorption or emission range. For example, when substituting monovalent cation Cs+ with phenyl-ethylammonium (PEA(+)) on fabricating 2D-CsPbI3, the photoluminescence peak processes a maximum regulation from 710 to 625 nm. Simultaneously, when slicing into 1D CsPbI3 nanowires, the light emission could also achieve a maximum blue shift from 700 to 600 nm. Herein, by using a ligand-assistant reprecipitation (LARP) method, oleic acid (OA) molecule is successfully inserted into the lattice of one-dimensional CsPbI3 nanowire (namely OA-CsPbI3), which presents a monochromatic yellow light emission at 558 nm with narrow emission-band (about 28 nm), and records high photoluminescence quantum yield (PLQY) of 94%. Such a yellow-light emission in single halide CsPbI3 systems has never been discovered before. Meanwhile, a shallow energy level in the OA-CsPbI3 nanowire is further identified by the ultrafast transient absorption (TA) and first-principle calculation, which helps the photoexcited carriers bypass the trap state level in the bandgap and enhances the radiative excitons lifetime with maximum binding energy up to 212.5 meV. What's more, the excellent thermal and moisture stabilities of the newly formed one-dimensional OA-CsPbI3 nanowire indicate a promising application prospect in the field of luminescent devices.

Keyword:

New structure Quantum confinement effect Photoluminescence quantum yield Binding energy Nanowire Single halide yellow light-emitting

Author Community:

  • [ 1 ] [Hu, Jingcong]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 2 ] [Zhang, Xuetao]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 3 ] [Lu, Yue]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 4 ] [Tian, Bohai]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 5 ] [Selvakumar, Karuppaiah]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 6 ] [Sui, Manling]Beijing Univ Technol, Fac Mat & Mfg, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 7 ] [Bi, Chenghao]Univ Sci & Technol, Inst Adv Mat & Technol, Beijing 100083, Peoples R China
  • [ 8 ] [Yao, Zhiwei]Univ Sci & Technol, Inst Adv Mat & Technol, Beijing 100083, Peoples R China
  • [ 9 ] [Tian, Jianjun]Univ Sci & Technol, Inst Adv Mat & Technol, Beijing 100083, Peoples R China
  • [ 10 ] [Zhou, Wencai]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 11 ] [Zheng, Zilong]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 12 ] [Tang, Ying]Nanjing Univ, Sch Phys, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China
  • [ 13 ] [Wang, Xiaoyong]Nanjing Univ, Sch Phys, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China
  • [ 14 ] [Tang, Ying]Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Peoples R China
  • [ 15 ] [Wang, Xiaoyong]Nanjing Univ, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Peoples R China
  • [ 16 ] [Lu, Feng]Nankai Univ, Dept Elect Sci & Engn, Tianjin 300071, Peoples R China
  • [ 17 ] [Lu, Feng]Nankai Univ, Tianjin Key Lab Photoelect Thin Film Device & Tech, Tianjin 300071, Peoples R China

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Source :

APPLIED MATERIALS TODAY

ISSN: 2352-9407

Year: 2022

Volume: 29

8 . 3

JCR@2022

8 . 3 0 0

JCR@2022

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 6

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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