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Author:

Li, Qing-Yan (Li, Qing-Yan.) | Xu, Chunmei (Xu, Chunmei.) | Liang, Ya-Ru (Liang, Ya-Ru.) | Yang, Zhuo (Yang, Zhuo.) | LeGe, Niubu (LeGe, Niubu.) | Peng, Jian (Peng, Jian.) | Chen, Lijia (Chen, Lijia.) | Lai, Wei-Hong (Lai, Wei-Hong.) | Wang, Yun-Xiao (Wang, Yun-Xiao.) | Tao, Zhanliang (Tao, Zhanliang.) | Liu, Min (Liu, Min.) | Chou, Shulei (Chou, Shulei.)

Indexed by:

EI Scopus SCIE

Abstract:

Increasing generation of permanent magnet waste has resulted in an urgent need to preserve finite resources. Reforming these wastes as feedstock to produce renewables is an ideal strategy for addressing waste and energy challenges. Herein, our work reports a smart and sustainable strategy to convert iron in magnet wastes into Prussian blue analogues that can serve as cathode materials for sodium-ion batteries. Moreover, a method to control feed rates is proposed to generate high-quality materials with fewer [Fe(CN)6] vacancies at a feed rate of 3 mL min-1. The recycled Na1.46Fe[Fe(CN)6]0.85 center dot 0.15 shows low vacancies and excellent cycling stability over 300 cycles (89% capacity retention at 50 mA g-1). In operando, evidence indicates that high-quality Prussian blue allows fast sodium-ion mobility and a high degree of reversibility over the course of cycling, although with a three-phase-transition mechanism. This study opens up a future direction for magnet waste created with the expectation of being environmentally reused.

Keyword:

cathode materials recycle sodium-ion battery magnet waste Prussian blue

Author Community:

  • [ 1 ] [Li, Qing-Yan]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 2 ] [LeGe, Niubu]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 3 ] [Liu, Min]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 4 ] [Xu, Chunmei]Wenzhou Univ, Coll Chem & Mat Engn, Inst Carbon Neutralizat, Wenzhou 325035, Peoples R China
  • [ 5 ] [Yang, Zhuo]Wenzhou Univ, Coll Chem & Mat Engn, Inst Carbon Neutralizat, Wenzhou 325035, Peoples R China
  • [ 6 ] [LeGe, Niubu]Wenzhou Univ, Coll Chem & Mat Engn, Inst Carbon Neutralizat, Wenzhou 325035, Peoples R China
  • [ 7 ] [Chou, Shulei]Wenzhou Univ, Coll Chem & Mat Engn, Inst Carbon Neutralizat, Wenzhou 325035, Peoples R China
  • [ 8 ] [Liang, Ya-Ru]Xiangtan Univ, Sch Mat Sci & Engn, Xiangtan 411105, Peoples R China
  • [ 9 ] [Yang, Zhuo]Univ Wollongong, Inst Superconducting & Elect Mat, Australian Inst Innovat Mat, North Wollongong, NSW 2522, Australia
  • [ 10 ] [Peng, Jian]Univ Wollongong, Inst Superconducting & Elect Mat, Australian Inst Innovat Mat, North Wollongong, NSW 2522, Australia
  • [ 11 ] [Lai, Wei-Hong]Univ Wollongong, Inst Superconducting & Elect Mat, Australian Inst Innovat Mat, North Wollongong, NSW 2522, Australia
  • [ 12 ] [Wang, Yun-Xiao]Univ Wollongong, Inst Superconducting & Elect Mat, Australian Inst Innovat Mat, North Wollongong, NSW 2522, Australia
  • [ 13 ] [Tao, Zhanliang]Nankai Univ, Key Lab Adv Energy Mat Chem, Renewable Energy Convers & Storage Ctr, Coll Chem,Minist Educ, Tianjin 300071, Peoples R China
  • [ 14 ] [Chen, Lijia]Guangdong Acad Sci, Guangdong Key Lab Modern Control Technol, Inst Intelligent Mfg, Guangzhou 510000, Peoples R China

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Source :

ACS APPLIED MATERIALS & INTERFACES

ISSN: 1944-8244

Year: 2022

9 . 5

JCR@2022

9 . 5 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:66

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 17

SCOPUS Cited Count: 20

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 7

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