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Author:

Wang, Y. (Wang, Y..) | Wang, K. (Wang, K..) | Meng, J. (Meng, J..) | Ban, C. (Ban, C..) | Duan, Y. (Duan, Y..) | Feng, Y. (Feng, Y..) | Jing, S. (Jing, S..) | Ma, J. (Ma, J..) | Yu, D. (Yu, D..) | Gan, L. (Gan, L..) | Zhou, X. (Zhou, X..)

Indexed by:

EI Scopus SCIE

Abstract:

The development of advanced photocatalysts for CO2 reduction (CO2R) has attracted intensive interest but is severely plagued by the intrinsically narrow photo-responsive range, inefficient carrier separation of the current supports. Herein, the unconventional atomic surface concaves with Bi-O-Br complex vacancies on thin Bi5O7Br nanotubes were designed and successfully synthesized. This concave-rich structures provide electron localized enrichment regions that could address the above two issues simultaneously. The unique concaves serve as the active sites that enable the exceptional capacity for the capture and activation of CO2 and the formation of key intermediates. Ultimately, an ultrahigh CO yield rate of 30.96 μmol g−1 h−1 was obtained under ambient conditions without anchoring extra metal active species or any sacrificial agents. Our work not only provides a promising support but also proposes a unique structure to optimize the photocatalytic performance. © 2023 Elsevier Ltd

Keyword:

Atomic surface concave CO2 capture and activation Photocatalytic CO2 reduction Electron localized enrichment Bi5O7Br

Author Community:

  • [ 1 ] [Wang Y.]College of Physics and Center of Quantum Materials and Devices, Chongqing University, Chongqing, 401331, China
  • [ 2 ] [Wang K.]Beijing Key Laboratory of Microstructure and Property of Advanced Materials, Beijing University of Technology, Beijing, 100024, China
  • [ 3 ] [Meng J.]College of Physics and Center of Quantum Materials and Devices, Chongqing University, Chongqing, 401331, China
  • [ 4 ] [Ban C.]College of Physics and Center of Quantum Materials and Devices, Chongqing University, Chongqing, 401331, China
  • [ 5 ] [Duan Y.]College of Physics and Center of Quantum Materials and Devices, Chongqing University, Chongqing, 401331, China
  • [ 6 ] [Feng Y.]College of Physics and Center of Quantum Materials and Devices, Chongqing University, Chongqing, 401331, China
  • [ 7 ] [Jing S.]College of Physics and Center of Quantum Materials and Devices, Chongqing University, Chongqing, 401331, China
  • [ 8 ] [Ma J.]College of Physics and Center of Quantum Materials and Devices, Chongqing University, Chongqing, 401331, China
  • [ 9 ] [Yu D.]School of Chemistry and Chemical Engineering, Chongqing University, Chongqing, 401331, China
  • [ 10 ] [Gan L.]College of Physics and Center of Quantum Materials and Devices, Chongqing University, Chongqing, 401331, China
  • [ 11 ] [Gan L.]State Key Laboratory of Coal Mine Disaster Dynamics and Control, Chongqing University, Chongqing, 401331, China
  • [ 12 ] [Gan L.]Donghai Laboratory, Zhejiang, Zhoushan, 316021, China
  • [ 13 ] [Zhou X.]College of Physics and Center of Quantum Materials and Devices, Chongqing University, Chongqing, 401331, China
  • [ 14 ] [Zhou X.]State Key Laboratory of Coal Mine Disaster Dynamics and Control, Chongqing University, Chongqing, 401331, China
  • [ 15 ] [Zhou X.]Analytical and Testing Center, Chongqing University, Chongqing, 401331, China

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Source :

Nano Energy

ISSN: 2211-2855

Year: 2023

Volume: 109

1 7 . 6 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:26

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 49

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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