Ketyl　radicals　display　new　reactivities　beyond　the　intrinsic　electrophilicity　of　carbonyls.　Recently,　the　bloom　of　organic　electrosynthesis　has　fueled　the　evolution　of　the　generation　and　harnessing　of　ketyl　radcials　under　“greener”　conditions.　This　graphical　review　summarizes　these　electrochemical　advancements　into　three　major　categories:　cross-pinacol　couplings,　coupling　of　carbonyls　with　alkyl　radical　precursors,　and　coupling　of　carbonyls　with　unsaturated　systems　(alkenes,　alkynes,　cyanoarenes,　and　N-heterocycles).　©　2024　Georg　Thieme　Verlag.　All　rights　reserved.