A　simple　solvothermal　method　was　used　to　obtain　W–Mo　bimetallic　oxides　from　W–Mo　alloy　scrap,　and　pure　metal　powders　were　also　used　as　the　raw　materials　to　simulate　scrap.　The　products　had　a　sea　urchin-like　structure　with　abundant　oxygen　vacancies　and　the　products　prepared　at　low　temperatures　forms　a　sosoloid　resembling　orthorhombic　W0.4Mo0.6O3.　The　W–Mo　bimetallic　oxide　prepared　at　the　reaction　temperature　of　120　°C　exhibited　excellent　selective　adsorption　performance　for　methylene　blue　(MB),　which　the　adsorption　rate　of　MB　reached　99%　in　12 min　and　the　adsorption　rate　reached　90%　after　6　adsorption　cycles.　When　the　W–Mo　molar　ratio　is　1:3,　the　maximum　adsorption　capacity　of　sample　for　MB　can　reach　1148 mg‧g−1.　The　adsorption　process　followed　the　Langmuir　and　pseudo-second-order　models,　which　is　surface-controlled　monolayer　adsorption.　The　experimental　results　show　the　feasibility　of　preparing　W–Mo　bimetal　oxide　products　from　pure　materials　and　scrap.　The　process　is　simple　and　effective,　which　offered　a　potential　approach　for　secondary　resource　recycling　and　reusing.　©　Youke　Publishing　Co.,　Ltd　2024.