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Author:

Zhao, Z. (Zhao, Z..) | Peng, C. (Peng, C..) | Yin, Q. (Yin, Q..) | Wang, Y. (Wang, Y..) | Li, K. (Li, K..) | Liu, C. (Liu, C..) | Tian, Y. (Tian, Y..)

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EI Scopus SCIE

Abstract:

Local symmetry of crystal field is crucial for optical temperature sensitivity that based on the thermal couple levels of rare earth ions. In this work, Lu3+ ions were introduced to alter the local environment of Er3+ ions in oxyfluoride glass-ceramics. X-ray diffraction patterns and transmission electron microscope images show that Y5O4F7 nanocrystals are precipitated in glass-ceramics. Incorporation of rare-earth ions into the Y5O4F7 nanocrystals is confirmed by absorption and electron energy loss spectra. The Judd-Ofelt (J-O) theory analysis reveals that local symmetry of the crystal field around Er3+ decreasing due to Lu3+ co-doping. Temperature sensing property of the Y5O4F7: Er3+/Yb3+/Lu3+ nanocrystal incorporated glass-ceramic was investigated, and the optimal relative temperature sensitivity SR reaches 1.50 % K−1 in 0.25 mol.% Lu3+ doped specimen. Results show that the moderate addition of Lu3+ can improve the temperature sensitivity of glass-ceramic containing Y5O4F7:Er3+/Yb3+ nanocrystals, which provide a promising avenue for optical temperature sensing. © 2024 Elsevier Ltd and Techna Group S.r.l.

Keyword:

Optical thermometry Up-conversion emission Judd-ofelt Y5O4F7 nanocrystals Oxyfluoride glass-ceramic

Author Community:

  • [ 1 ] [Zhao Z.]School of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 2 ] [Zhao Z.]National Engineering Research Center of FPD Glass Technology, Xianyang, 712000, China
  • [ 3 ] [Peng C.]School of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 4 ] [Yin Q.]School of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 5 ] [Wang Y.]School of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 6 ] [Li K.]State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Hubei, 430070, China
  • [ 7 ] [Liu C.]State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Hubei, 430070, China
  • [ 8 ] [Tian Y.]School of Materials Science and Engineering, Beijing University of Technology, Beijing, 100124, China
  • [ 9 ] [Tian Y.]National Engineering Research Center of FPD Glass Technology, Xianyang, 712000, China

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Source :

Ceramics International

ISSN: 0272-8842

Year: 2024

Issue: 18

Volume: 50

Page: 33472-33479

5 . 2 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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