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Author:

Li Shufeng (Li Shufeng.) | Wang Li (Wang Li.) (Scholars:王丽) | Su Xuegiong (Su Xuegiong.) | Pan Yong (Pan Yong.) | Gao Dongwen (Gao Dongwen.) | Han Xiaowei (Han Xiaowei.)

Indexed by:

EI Scopus SCIE

Abstract:

Effects of Co concentration on the properties of ZnSe:Co films were investigated. The amorphous and crystalline (ZnSe)(1-x):Co-x (x = =0.1, 0.3, 0.5) thin films were grown on sapphire (Al2O3) substrates with temperature of 25 degrees C and 800 degrees C respectively by pulsed laser deposition. The X-ray diffraction analyses indicate that, with increasing Co concentration, the average grain size decrease whereas the microstrain and dislocation density increase. Meanwhile, the further investigation for crystalline thin films shows that the crystalline phase transform from single cubic zinc blende structure to a mixture structure containing a small amount of hexagonal wurtzite phase. The Raman spectra and X-ray photoelectron spectroscopy reveal that the Co atoms were incorporated into ZnSe lattice and the samples reached an overdoping state when the x value surpassed 0.3. With increasing Co concentration, the average transmittance of films decreased due to the Co impurities un-incorporating into ZnSe lattice. Meanwhile, the band gap E-g values of films increased from 3.17 eV to 3.50 eV for T-S = =25 degrees C and from 2.86 eV to 3.34 eV for T-S = =800 degrees C. The large E-g values with regard to that of undoped bulk ZnSe (similar to 2.7 eV) can be attributed to the Co doping and quantum confinement effect. Moreover, the refractive index of the films increased by improving Co concentration. The dispersion energy E-d, oscillator energy E-o, static refractive index n(0), static dielectric constant epsilon(0), oscillator strength S-o and oscillator wavelength lambda(o) are analyzed by a single oscillator model. All these parameters were found to be dependent upon the Co concentration in the (ZnSe)(1-x):Co-x thin films.

Keyword:

PLD (ZnSe)(1-x):Co-x Thin film Optical properties Structure

Author Community:

  • [ 1 ] [Li Shufeng]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 2 ] [Wang Li]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 3 ] [Su Xuegiong]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 4 ] [Pan Yong]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 5 ] [Gao Dongwen]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 6 ] [Han Xiaowei]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China
  • [ 7 ] [Li Shufeng]Chinese Peoples Police Univ, Fundament Dept, Langfang 065000, Peoples R China

Reprint Author's Address:

  • 王丽

    [Wang Li]Beijing Univ Technol, Coll Appl Sci, Beijing 100124, Peoples R China

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Source :

THIN SOLID FILMS

ISSN: 0040-6090

Year: 2019

Volume: 692

2 . 1 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:211

JCR Journal Grade:3

Cited Count:

WoS CC Cited Count: 15

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 8

Affiliated Colleges:

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