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Abstract:
Hydrothermal stability of the Cu(A, N, Cl or S)/SAPO.34 samples derived from different Cu precursors (A: Cuacetate; N: Cu-nitrate; Cl: Cu-chloride; and S: Cu-sulfate) was investigated. The physical and chemical properties of the samples were investigated by various analytical techniques, and their catalytic activities for NO conversion and NH3 oxidation were evaluated. The results of NH3-SCR activity show that the Cu(A)/SAPO-34 sample was better than that of the Cu(N, Cl or S)/SAPO-34 sample, which was due to the existence of a less amount of CuO species and a more amount of the isolated Cu2+ species. Moreover, catalytic activities of all aged catalysts decreased in the whole temperature range, which was attributed to the drop in the amount of isolated Cu2+ species in the hydrothermally treated Cu/SAPO-34 samples. After hydrothermal aging treatment, part of the isolated Cu2+ was transformed to CuO, leading to structural instability and deactivation of the catalysts.
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MICROPOROUS AND MESOPOROUS MATERIALS
ISSN: 1387-1811
Year: 2019
Volume: 278
Page: 423-434
5 . 2 0 0
JCR@2022
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:211
JCR Journal Grade:1
Cited Count:
WoS CC Cited Count: 29
SCOPUS Cited Count: 30
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 9
Affiliated Colleges: