Hybrid　materials　(Z1-BMMs)　were　prepared　through　grafting　(2S,　2＇S)-N,N＇-([2,2＇-bipyridine]-3,3＇-diyl)bis　(pyrrolidine-2-carboxamide)　(Z1)　onto　the　surface　of　bimodal　mesoporous　silicas　(BMMs).　Their　structural　properties　and　textural　parameters　were　characterized　with　XRD,　SEM,　N-2　sorption,　UV-vis,　FT-IR,　TGA,　elemental　analysis　and　fluorescence　emission.　Fluorescence　profiles　of　the　obtained　Z1-BMMs　showed　the　remarkable　blue-shift　of　characteristic　peak　in　emission　spectra　compared　to　that　of　pure　21,　while　their　fluorescence　intensity　and　peak　position　strongly　depended　on　mass　ratios　of　Z1　to　BMMs.　Meanwhile,　their　catalytic　performances　for　asymmetric　aldol　reaction　presented　good　activities　(yield　up　to　75%)　and　high　stereo　selectivities　fee　up　to　82%),　however,　Z1-BMMs,　if　reused　more　than　2　times,　showed　rapid　catalytic　deactivation.