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Author:

Li, Shuangye (Li, Shuangye.) | Li, Jian (Li, Jian.) | Liang, Wenjun (Liang, Wenjun.) (Scholars:梁文俊) | Cai, Jianyu (Cai, Jianyu.) | Guo, Ruixue (Guo, Ruixue.)

Indexed by:

EI Scopus SCIE

Abstract:

Cerium oxide (CeO2) was added to modified Ru/TiO2 catalyst by a two-step impregnation method for selective catalytic oxidation of ammonia (NH3-SCO). The low-temperature NH3 oxidation activity and N2 selectivity of the 1Ru/xCe-TiO2 catalyst were investigated with the result that both SCO activity and N2 selectivity were influenced by the amount of Ce. Specifically, the presence of 5 wt% CeO2 demonstrated a great promoting effect on both parameters, reaching an NH3 conversion and N2 selectivity of 97 % and 93 % at 180 degrees C, respectively. Various characterization methods indicated that the presence of CeO2 regulates the dispersion of the 1Ru/xCeTiO2 catalysts, changes the amount, strength and ratio of strong and weak acid sites on the catalyst surface, and promotes the formation of Ru-O-Ce bonds through the interaction between Ce and Ru species, which facilitates electron transfer and oxygen vacancy formation, thereby enhancing the oxidation ability of the catalysts. Furthermore, the results of in situ diffuse reflectance infrared Fourier transform spectroscopy indicated that the NH3-SCO reaction over the 1Ru/xCe-TiO2 catalysts follows the "internal" selective catalytic reduction (i-SCR) mechanism, involving the oxidation of NH3 into nitric oxide (NO) species and the reaction of -NH2 with in situformed NO to form N2.

Keyword:

Ammonia slip Cerium Catalysts Surface acidity i-SCR mechanism Ruthenium

Author Community:

  • [ 1 ] [Li, Shuangye]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Jian]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 3 ] [Liang, Wenjun]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 4 ] [Cai, Jianyu]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 5 ] [Guo, Ruixue]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Liang, Wenjun]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China;;[Cai, Jianyu]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China;;

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Source :

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING

ISSN: 2213-2929

Year: 2024

Issue: 5

Volume: 12

7 . 7 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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