Barium　titanate　(BaTiO3)　piezoelectric　ceramics　with　triply　periodic　minimal　surface　(TPMS)　structures　have　been　frequently　used　in　filters,　engines,　artificial　bones,　and　other　fields　due　to　their　high　specific　surface　area,　high　thermal　stability,　and　good　heat　dissipation.　However,　only　a　limited　number　of　studies　have　analyzed　the　effect　of　various　parameters,　such　as　different　wall　thicknesses　and　porosities　of　TPMS　structures,　on　ceramic　electromechanical　performance.　In　this　study,　we　first　employed　vat　photopolymerization　(VPP)　three-dimensional　(3D)　printing　technology　to　fabricate　high-performance　BaTiO3　ceramics.　We　investigated　the　slurry　composition　design　and　forming　process　and　designed　a　stepwise　sintering　postprocessing　technique　to　achieve　a　density　of　96.3%　and　a　compressive　strength　of　250　+/-　25　MPa,　with　the　piezoelectric　coefficient　(d33)　reaching　263　pC/N.　Subsequently,　we　explored　the　influence　of　three　TPMS　structures,　namely,　diamond,　gyroid,　and　Schwarz　P,　on　the　piezoelectric　and　mechanical　properties　of　BaTiO3　ceramics,　with　the　gyroid　structure　identified　as　exhibiting　optimal　performance.　Finally,　we　examined　the　piezoelectric　and　mechanical　properties　of　BaTiO3　ceramics　with　the　gyroid　structure　of　varying　wall　thicknesses　and　porosities,　thus　enabling　the　modulation　of　ceramic　electromechanical　performance.