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Author:

Yu, Lichao (Yu, Lichao.) | Lu, Qingmei (Lu, Qingmei.) | Cong, Liying (Cong, Liying.) | Yang, Xinyuan (Yang, Xinyuan.) | Liu, Weiqiang (Liu, Weiqiang.) | Dong, Gaihua (Dong, Gaihua.) | Huang, Shulin (Huang, Shulin.) | Deng, Yuan (Deng, Yuan.) | Meng, Lijuan (Meng, Lijuan.) | Liu, Youhao (Liu, Youhao.) | Yi, Xiaofei (Yi, Xiaofei.) | Wu, Yufeng (Wu, Yufeng.) | Yue, Ming (Yue, Ming.)

Indexed by:

EI Scopus SCIE

Abstract:

The grinding sludge of grain boundary diffusion Nd-Fe-B magnet is rich in heavy rare earth and has a typical core–shell microstructure. In this work, an ultra-short process was developed to realize green, in-situ regeneration of the sludge and efficient reuse of heavy rare earth elements. The regenerated magnets showed excellent magnetic performance and good temperature stability which were fabricated after the purification of sludge, composition regulation with rare earth-rich compounds, Nd42.1FebalB0.79, NdHx, (PrNd)Hx, and sintering. Especially, the magnet prepared by using Nd42.1FebalB0.79 alloy had significant property recovery, where remanence and coercivity were restored to 12.8 kG, and 20.6 kOe, respectively, reaching 97.7 % and 162.5 % of the original magnet. The magnetization reversal behavior and the coercivity mechanism were analyzed to keep the nucleation mechanism, and the high coercivity stemmed from the repair and optimization of the grain boundary by introducing rare earth-rich alloys, the full utilization of heavy rare earth elements, and the core–shell microstructure rooted in the sludge as well. © 2024

Keyword:

Neodymium alloys Iron alloys Potassium alloys Remanence Sintering Neodymium compounds Praseodymium alloys Mercury amalgams Magnetization reversal Hafnium alloys

Author Community:

  • [ 1 ] [Yu, Lichao]College of Materials and Engineering, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing; 100124, China
  • [ 2 ] [Lu, Qingmei]College of Materials and Engineering, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing; 100124, China
  • [ 3 ] [Lu, Qingmei]State Key Laboratory of Rare Earth Permanent Magnetic Materials, China
  • [ 4 ] [Cong, Liying]College of Materials and Engineering, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing; 100124, China
  • [ 5 ] [Yang, Xinyuan]College of Materials and Engineering, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing; 100124, China
  • [ 6 ] [Liu, Weiqiang]College of Materials and Engineering, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing; 100124, China
  • [ 7 ] [Liu, Weiqiang]State Key Laboratory of Rare Earth Permanent Magnetic Materials, China
  • [ 8 ] [Dong, Gaihua]Baotou Inst Magnetic New Material Co., Ltd., Inner Mongolia, Baotou; 014030, China
  • [ 9 ] [Huang, Shulin]Baotou Inst Magnetic New Material Co., Ltd., Inner Mongolia, Baotou; 014030, China
  • [ 10 ] [Deng, Yuan]Inner Mongolia Rare Earth Functional Materials Innovation Center Co., Ltd., Inner Mongolia, Baotou; 014030, China
  • [ 11 ] [Meng, Lijuan]Inner Mongolia Rare Earth Functional Materials Innovation Center Co., Ltd., Inner Mongolia, Baotou; 014030, China
  • [ 12 ] [Liu, Youhao]Earth-Panda Advanced Magnetic Materials Co., Ltd., Lujiang County, Anhui, Hefei; 231500, China
  • [ 13 ] [Liu, Youhao]State Key Laboratory of Rare Earth Permanent Magnetic Materials, China
  • [ 14 ] [Yi, Xiaofei]Earth-Panda Advanced Magnetic Materials Co., Ltd., Lujiang County, Anhui, Hefei; 231500, China
  • [ 15 ] [Yi, Xiaofei]State Key Laboratory of Rare Earth Permanent Magnetic Materials, China
  • [ 16 ] [Wu, Yufeng]College of Materials and Engineering, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing; 100124, China
  • [ 17 ] [Yue, Ming]College of Materials and Engineering, Key Laboratory of Advanced Functional Materials, Ministry of Education of China, Beijing University of Technology, Beijing; 100124, China
  • [ 18 ] [Yue, Ming]State Key Laboratory of Rare Earth Permanent Magnetic Materials, China

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Source :

Journal of Magnetism and Magnetic Materials

ISSN: 0304-8853

Year: 2024

Volume: 610

2 . 7 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 9

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